Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant

• US 9,827,185 B2
• Filed: 08/02/2013
• Issued: 11/28/2017
• Est. Priority Date: 08/02/2012
• Status: Active Grant

• Current Assignee: L'Oreal SA
• Original Assignee: L'Oreal SA
• Inventors: Charrier, Delphine, Fack, Geraldine
• Primary Examiner(s): ELHILO, EISA B
• Application Number:
  US14/418,762
• Publication Number:
  US 20150202142A1
• Time in Patent Office: 1,579 Days
• Field of Search: 8405
• CPC Class Codes: A61K 2800/4324 in preparations for permanently dyeing the hair
• CPC Class Codes: A61K 2800/596 Mixtures of surface active compounds
• CPC Class Codes: A61K 2800/882 Mixing prior to application
• CPC Class Codes: A61K 8/22 Peroxides; Oxygen; Ozone
• CPC Class Codes: A61K 8/31 Hydrocarbons
• CPC Class Codes: A61K 8/39 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61K 8/415 Aminophenols
• CPC Class Codes: A61K 8/442 substituted by amido group(s)
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/737 Galactomannans, e.g. guar; Derivatives thereof
• CPC Class Codes: A61K 8/817 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
• CPC Class Codes: A61K 8/86 Polyethers
• CPC Class Codes: A61K 8/92 Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
• CPC Class Codes: A61Q 5/10 Preparations for permanently dyeing the hair
• CPC Class Codes: B65D 25/04 Partitions
• CPC Class Codes: B65D 81/32 for packaging two or more different materials which must be maintained separate prior to use in admixture containers with removable or destructible partitions B65D25/08 ; closures combined with auxiliary containers B65D51/28; in aerosol containers B65D83/682; amalgam capsules A61C5/66; containers for pharmaceutical purposes A61J1/20, A61M5/19; medical syringes A61M3/005, resin cartridges for grouting anchoring-bolts in mines E21D20/026

Abstract

The subject of the present invention is a composition for dyeing human keratin fibres such as the hair, comprising: (a) at least one colouring agent chosen from oxidation dye precursors, direct dyes and mixtures thereof; (b) at least one amphoteric or zwitterionic surfactant; (c) at least one non-ionic surfactant; (d)at least one anionic surfactant (e) one or more fatty substances at a total content of at least 10% by weight relative to the weight of the composition; (f) at least one cationic polymer; (g) at least one oxidizing agent other than atmospheric oxygen. The present invention also relates to a process for dyeing human keratin fibres, in which this composition is applied to said fibres, and also to a suitable multicompartment device.

Claims

1. A composition for dyeing keratin fibers, comprising:

at least one coloring agent chosen from oxidation dye precursors, direct dyes, or mixtures thereof;

at least one amphoteric or zwitterionic surfactant;

at least one non-ionic surfactant;

at least one anionic surfactant;

at least one fatty substance chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, polydecenes, or hydrogenated polyisobutene, present in an amount of at least 10% by weight, relative to the weight of the composition;

at least one cationic polymer; and

at least one oxidizing agent other than atmospheric oxygen

wherein the amphoteric surfactant and anionic surfactant are present in a weight ratio ranging from 0.1 to 10.

2. The composition according to claim 1, wherein at least one coloring agent is an oxidation dye precursor, chosen from oxidation bases or addition salts thereof.

3. The composition according to claim 2, wherein the oxidation dye precursors are chosen from couplers and acid addition salts thereof.

4. The composition according to claim 1, wherein the at least one coloring agent is a direct dye chosen from cationic direct dyes;

azo direct dyes;

(poly)methin dyes;

carbonyl dyes;

azine dyes;

nitro (hetero)aryl dyes;

tri(hetero)arylmethane dyes;

porphyrins;

phthalocyanines, natural direct dyes, or mixtures thereof.

5. The composition according to claim 1, wherein at least one coloring agent is chosen from direct dyes chosen from hydrazono cationic dyes of formulae (II) or (Ill), or azo cationic dyes of formulae (IV) or (V) below:

Het⁺-C(R_a)═

N—

N(R_b)—

Ar, Q⁻

 

 

(II)

Het⁺-N(R_a)—

N═

C(R_b)—

Ar, Q⁻

 

 

(III)

Het⁺-N═

N—

Ar, Q⁻

 

 

(IV)

Ar⁺—

N═

N—

Ar″

, Q⁻

 

 

(V)

wherein;

Her⁺ is a cationic heteroaryl radical, optionally substituted;

Ar⁺ is an aryl radical carrying an exocyclic cationic charge;

Ar is chosen from an aryl group, optionally substituted, or a julolidine group;

Ar″

is a (hetero)aryl group, optionally substituted;

R_a and R_b, which may be identical or different, are chosen from a hydrogen atom or a (C₁-C₈)alkyl group which is optionally substituted;

or R_a with a substituent of Her⁺ and/or R_b, with a substituent of Ar, form, together with the atoms which bear them, a (hetero)cycloalkyl; and

Q⁻

is an organic or inorganic anionic counterion;

wherein the cationic direct dyes of formula (II) to (V) optionally carry endocyclic cationic charges.

6. A composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is chosen from derivatives of optionally quaternized aliphatic secondary or tertiary amines, in which derivatives the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group.

7. The composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is chosen from the following compounds:

(C₈-C₂₀)alkylbetaines,

(C₈-C₂₀)alkylsulfobetaines,

(C₈-C₂₀)alkylamido(C₃-C₈)alkylbetaines,

(C₈-C₂₀)alkylamido(C₆-C₈)alkylsulfobetaines,

the compounds of following structure (B1);

R_a—

C(O)—

NH—

CH₂—

CH₂—

N⁺(R_b)(R_c)—

CH₂C(O)O⁻

, M⁺, X⁻

 

 

(B1)

wherein

R_a represents a C₁₀-C₃₀ alkyl or alkenyl group derived from an acid R_a—

COOH, or a heptyl, nonyl or undecyl group;

R_b represents a β

-hydroxyethyl group; and

R_c represents a carboxymethyl group;

M⁺ represents a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine, and

X⁻

represents an organic or inorganic anionic counterion, or alternatively M⁺ and X⁻

are absent,

the compounds of following structure (B2);

R_a′

—

C(O)—

NH—

CH₂—

CH₂—

N(B)(B′

) 

 

(B2)

wherein

B is the group —

CH₂—

CH₂—

O—

X′

;

B′

is the group —

(CH₂)_zY′

, with z equal to the integer 1 or 2;

X′

is chosen from the groups —

CH₂—

C(O)OH, —

CH₂—

C(O)OZ′

, —

CH₂—

CH₂—

C(O)OH, —

CH₂—

CH₂—

C(O)OZ′

, or a hydrogen atom;

Y′

is chosen from the groups —

C(O)OH, —

C(O)OZ′

, —

CH₂—

CH(OH)—

SO₃H or —

CH₂—

CH(OH)—

SO₃—

Z′

;

Z′

is chosen from cationic counterions derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine;

R_a′

is chosen from C₁₀-C₃₀ alkyl or alkenyl groups of an acid R_a′

—

C(O)OH, alkyl groups, or unsaturated C₁₇ groups, and

the compounds of formula (B′

2);

R_a″

—

NH—

CH(Y″

)—

(CH₂)n-C(O)—

NH—

(CH₂)n′

-N(R_d)(R_e) 

 

(B′

2)

wherein;

Y″

is chosen from the groups —

C(O)OH, —

C(O)OZ″

, —

CH₂—

CH(OH)—

SO₃H or —

CH₂—

CH(OH)—

SO₃—

Z″

;

R_d and R_e, independently of each other, are C₁-C₄ alkyl or hydroxyalkyl radicals;

Z″

is chosen from cationic counterions derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine;

R_a″

is chosen from C₁₀-C₃₀ alkyl or alkenyl groups of an acid R_a″

—

C(O)OH; and

n and n′

, independently of each other, are integers ranging from 1 to 3.

8. The composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is present in an amount ranging from about 0.1% to about 30% by weight, relative to the total weight of the composition.

9. The composition according to claim 1, wherein the at least one non-ionic surfactant is chosen from oxyalkylenated or glycerolated non-ionic surfactants, or mixtures thereof:

oxyalkylenated (C₈-C₂₄)alkylphenols;

saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C₈-C₃₀ alcohols;

saturated or unsaturated, linear or branched, oxyalkylenated C₈-C₃₀ fatty acid amides;

esters of saturated or unsaturated, linear or branched, C₈-C₃₀ acids and of polyethylene glycols;

esters of saturated or unsaturated, linear or branched, C₈-C₃₀ acids and of sorbitol;

fatty acid esters of sucrose;

(C₈-C₃₀)alkylpolyglycosides, (C₈-C₃₀)alkenylpolyglycosides, optionally oxyalkylenated (0 to 10 oxyalkylene units) and comprising 1 to 15 glucose units, (C₈-C₃₀)alkylglucoside esters;

oxyethylenated and saturated or unsaturated vegetable oils;

condensates of ethylene oxide and/or of propylene oxide, inter alis, alone or as mixtures;

N—

(C₈-C₃₀ )alkylglucamine derivatives and N—

(C₈- C₃₀)acyl-methylglucamine derivatives;

aldobionamides;

amine oxides;

oxyethylenated and/or oxypropylenated silicones;

or mixtures thereof.

10. The composition according to claim 1, wherein the at least one non-ionic surfactant is present in an amount ranging from about 0.1% to about 30% by weight, relative to the total weight of the composition.

11. The composition according to claim 1, wherein the at least one anionic surfactant is chosen from alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkyl sulfonates, alkylamide sulfonates, alkylaryl sulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acyl sarcosinates, acyl glutamates, alkyl sulfosuccinamates, acyl isethionates and N-acyl taurates;

salts of alkyl monoesters of polyglycoside-polycarboxylic acids, acyl lactylates, salts of D-galactoside uronic acids, salts of alkyl ether carboxylic acids, salts of alkylaryl ether carboxylic acids, salts of alkylamido ether carboxylic acids, and the corresponding non-salified forms thereof, and the alkyl and acyl groups thereof comprising from 6 to 40 carbon atoms, wherein the aryl group is a phenyl group.

12. The composition according to claim 1, wherein the at least one anionic surfactant is present in an amount ranging from about 0.1% to about 30% by weight, relative to the total weight of the composition.

13. The composition according to claim 1, wherein the at least one fatty substance is present in an amount ranging from about 15% to about 70% by weight, relative to the total weight of the composition.

14. The composition according to claim 1, wherein the at least one cationic polymer has a charge density of at least 1 meq/g.

15. The composition according to claim 1, wherein the at least one cationic polymer is chosen from the following polymers, alone or as mixtures:

(1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides, and comprising at least one of the units of formula (I), (II), (Ill) or (IV) below;

16. The composition according to claim 1, wherein the at least one cationic polymer is present in an amount ranging from about 0.01% to about 10% by weight, relative to the weight of the composition.

17. A process for dyeing keratin fibers, comprising:

(a) preparing a dye composition by mixing;

a first composition free of oxidizing agent other than atmospheric oxygen, comprising at least one coloring agent chosen from oxidation dye precursors, direct dyes and mixtures thereof; and

a second composition comprising at least one oxidizing agent other than atmospheric oxygen;

wherein at least one of the first or second compositions comprises at least one fatty substance chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, Polvdecenes, or hydrogenated polyisobutene, at least one cationic polymer, and at least one amphoteric or zwitterionic surfactant;

wherein the resulting mixture has a total fatty substance content of at least about 10% by weight relative to the weight of the mixture;

wherein the amphoteric surfactant and anionic surfactant are present in a weight ratio ranging from 0.1 to 10; and

(b) applying said dye composition to said keratin fibers.

18. A device for mixing and using a composition for dyeing keratin fibers, comprising:

a first compartment containing a composition free of oxidizing agent other than atmospheric oxygen, comprising at least one coloring agent chosen from oxidation dye precursors, direct dyes or mixtures thereof; and

a second compartment containing an oxidizing composition;

wherein at least one of the compositions comprises at least one fatty substance chosen from liquid paraffins, petroleum jelly, liquid petroleum jelly, polvdecenes, or hydrogenated polyisobutene, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant, at least one anionic surfactant;

wherein the amphoteric surfactant and anionic surfactant are present in a weight ratio ranging from 0.1 to 10; and

wherein the composition in the first compartment and the composition in the second compartment are mixed before use.