Polarizing plate and liquid crystal display including the same

• US 9,835,771 B2
• Filed: 11/25/2015
• Issued: 12/05/2017
• Est. Priority Date: 11/26/2014
• Status: Active Grant

• Current Assignee: Samsung SDI Company Limited
• Original Assignee: Samsung SDI Company Limited
• Inventors: Shin, Kwang Ho, Park, Eun Su, Shin, Dong Yoon
• Primary Examiner(s): Font, Frank
• Application Number:
  US14/952,795
• Publication Number:
  US 20160146980A1
• Time in Patent Office: 741 Days
• Field of Search: 35948907, 359507, 359513, 349117, 349118
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 1/18 Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films G02B1/16 takes precedence
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001
• CPC Class Codes: G02F 1/133528 Polarisers
• CPC Class Codes: G02F 1/13363 Birefringent elements, e.g. for optical compensation

Abstract

A polarizing plate and a liquid crystal display including the polarizing plate include: a polarizer; and a surface protective film on a first surface of the polarizer, and the surface protective film includes a first protective film on the first surface of the polarizer, and a primer layer on at least one surface of the first protective film, a refractive index ratio of the first protective film to the primer layer satisfying the equation: 0.6<R₁/R₂<1.0, where R₁ is an index of refraction of the primer layer, and R₂ is an index of refraction of the first protective film, and the first protective film has an in-plane retardation (Re) of about 500 nm or less and an out-of-plane retardation (Rth) of about 10,000 nm or less at a wavelength of 550 nm.

Claims

1. A polarizing plate comprising:

a polarizer; and

a surface protective film on a first surface of the polarizer,

wherein the surface protective film comprises a first protective film on the first surface of the polarizer, and a primer layer on at least one surface of the first protective film,

a refractive index ratio of the first protective film to the primer layer satisfying Equation 1;

0.6<

R₁/R₂<

1.0,

where R₁ is an index of refraction of the primer layer and R₂ is an index of refraction of the first protective film,

the first protective film having an in-plane retardation of about 500 nm or less and an out-of-plane retardation of about 10,000 nm or less at a wavelength of 550 nm, as respectively represented by Equation 2;

Re=(nx−

ny)×

d,

and Equation 3;

Rth=((nx+ny)/2−

nz)×

d,

where Re is the in-plane retardation, Rth is the out-of-plane retardation, nx, ny, and nz are indices of refraction at a wavelength of 550 nm in the x-, y- and z-axis directions, respectively, of the first protective film, and d is a thickness of the first protective film.

2. The polarizing plate according to claim 1, wherein the primer layer has a thickness of about 5 nm to about 200 nm.

3. The polarizing plate according to claim 1, wherein the primer layer has an index of refraction of about 1.0 to about 1.6.

4. The polarizing plate according to claim 1, wherein the primer layer comprises silica particles.

5. The polarizing plate according to claim 4, wherein the silica particles have an average particle diameter of about 0.001 μ

m to about 10 μ

m.

6. The polarizing plate according to claim 4, wherein the silica particles are present in an amount of about 0.1 wt % to about 20 wt % in the primer layer.

7. The polarizing, plate according to claim 1, wherein the first protective film has a ratio of machine direction elongation to transverse direction elongation of about 1:

0.8 to about 1;

1.2.

8. The polarizing plate according to claim 1, wherein the first protective film has a ratio of machine direction elongation to transverse direction elongation of about 1:

1 and a degree of biaxiality of about 1.0 or more at a wavelength of 550 nm, as represented by Equation 4;

NZ=(nx−

nz)/(nx−

ny),

where NZ is the degree of biaxiality, and nx, ny, and nz are indices of refraction at a wavelength of 550 nm in the x-, y- and z-axis directions, respectively, of the first protective film.

9. The polarizing plate according to claim 1, wherein the first protective film has nx-ny of about 0 to about 0.1, and a degree of biaxiality of about 5.0 or more, as represented by Equation 4:

NZ=(nx−

nz)/(nx−

ny),

where NZ is the degree of biaxiality, and nx, ny, and nz are the indices of refraction at a wavelength of 550 nm in the x-, y- and z-axis directions, respectively, of the first protective film.

10. The polarizing plate according to claim 1, wherein the polarizing plate has a variation rate of transmittance of about 0.1% to about 1.8%, as represented by Equation 5:

Variation rate of transmittance (%)=(T_B−

T_A)/T_A×

100,

where T_A is an initial transmittance of the polarizing plate, and T_B is a transmittance of the polarizing plate after being maintained at 85°

C. for 500 hour.

11. The polarizing plate according to claim 1, wherein the surface protective film has a transmittance of about 92% or greater.

12. The polarizing plate according to claim 1, wherein the first protective film is a non-birefringent film.

13. The polarizing plate according to claim 1, wherein the first protective film comprises at least one resin selected from the group consisting of polyester resins, (meth)acrylic resins, and cyclic polyolefin resins.

14. The polarizing plate according to claim 1, further comprising a second protective film on a second surface of the polarizer opposite the first surface.

15. The polarizing plate according to claim 14, wherein the second protective film comprises at least one resin selected from the group consisting of cellulose resins, polyester resins, cyclic polyolefin resins, polycarbonate resins, polyethersulfone resins, polysulfone resins, polyimide resins, polyimide resins, polyolefin resins, polyarylate resins, polyvinyl alcohol resins, polyvinyl chloride resins, and polyvinylidene chloride resins.

16. A liquid crystal display comprising the polarizing plate according to claim 1.