Window with UV-treated low-E coating and method of making same

• US 9,919,959 B2
• Filed: 05/31/2012
• Issued: 03/20/2018
• Est. Priority Date: 05/31/2012
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Inventors: Krasnov, Alexey, Imran, Muhammad, Den Boer, Willem, O'Connor, Kevin
• Primary Examiner(s): MCCORMACK, JASON L
• Application Number:
  US13/484,894
• Publication Number:
  US 20130320241A1
• Time in Patent Office: 2,119 Days
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 2217/74 UV-absorbing coatings
• CPC Class Codes: C03C 2218/32 After-treatment

Abstract

A coated article includes a low-emissivity (low-E) coating supported by a substrate (e.g., glass substrate) for use in a window, where the low-E coating is exposed to ultraviolet (UV) radiation in order to improve the coating'"'"'s and thus the coated article'"'"'s electrical, optical and/or thermal blocking properties. Exposing the low-E coating to UV radiation, e.g., emitted from a UV lamp(s) and/or UV laser(s), allows for selective heating of a contact/seed layer which transfers energy to the adjacent IR reflecting layer.

Claims

1. A method of making a coated article for use in a window, the method comprising:

having a coated article including a glass substrate that supports a low-emissivity (low-E) coating comprising at least one layer comprising silver located directly on and contacting a contact layer comprising zinc oxide that can absorb ultraviolet (UV) radiation, the low-E coating further comprising a dielectric layer between the contact layer comprising zinc oxide and the glass substrate, and an upper dielectric layer located over the layer comprising silver so that the layer comprising silver is located between the upper dielectric layer and the glass substrate;

directing UV radiation from at least one UV source toward the coating and exposing the coating to UV radiation in order to reduce a sheet resistance of the coating and/or increase visible transmission of the coating; and

wherein the coated article has a visible transmission of at least about 50% after said exposing.

2. The method of claim 1, wherein the UV source comprises at least one UV emitting lamp.

3. The method of claim 1, wherein the UV source comprises at least one UV emitting laser.

4. The method of claim 1, wherein said exposing the coating to UV radiation reduces the sheet resistance of the coating by at least one ohm/square.

5. The method of claim 1, wherein the layer comprising zinc oxide has a bandgap of from about 3.2 to 3.4 eV.

6. The method of claim 1, wherein the contact layer comprises zinc stannate.

7. The method of claim 1, wherein the coating has a sheet resistance (R_s) of no greater than 10 ohms/square after said UV exposing.

8. The method of claim 1, wherein said exposing the coating to UV radiation increases the visible transmission of the coated article by at least 1%.

9. The method of claim 1, further comprising, after said exposing, coupling the substrate with the coating thereon to another substrate in making an insulating glass (IG) window unit.

10. The method of claim 1, wherein radiation emitted from the source consists essentially of UV radiation.

11. The method of claim 1, where the coating further comprises a layer comprising an oxide of Ni and/or Cr located over and directly contacting the layer comprising silver.

12. The method of claim 1, wherein the dielectric layer and the upper dielectric layer each comprise silicon nitride.

13. The method of claim 1, wherein the source and the coating are located on the same side of the substrate.

14. A method of making a coated article for use in a window, the method comprising:

having a coated article including a glass substrate that supports a low-E coating comprising at least one substantially metallic layer comprising silver located directly on and contacting a contact layer comprising zinc oxide that has a bandgap of from 3.2 to 3.4 eV, the low-E coating further comprising a dielectric layer between the contact layer comprising zinc oxide and the glass substrate, and an upper dielectric layer located over the layer comprising silver so that the layer comprising silver is located between the upper dielectric layer and the glass substrate;

directing UV radiation from at least one UV source toward the coating and exposing the coating to UV radiation in order to reduce a sheet resistance of the coating and increase visible transmission of the coating; and

wherein the coated article has a visible transmission of at least about 50% after said exposing.

15. The method of claim 14, wherein the UV source comprises at least one UV emitting lamp and/or laser.

16. The method of claim 14, wherein said exposing the coating to UV radiation reduces the sheet resistance of the substantially metallic layer by at least one ohm/square.