Alkali metal-modified vanadium-phosphorus oxide (VPO) catalyst

• US 9,931,618 B2
• Filed: 03/30/2015
• Issued: 04/03/2018
• Est. Priority Date: 04/02/2014
• Status: Active Grant

• Current Assignee: Clariant International AG (Clariant AG)
• Original Assignee: Clariant International AG (Clariant AG)
• Inventors: Cotter, Thomas, Reitzmann, Andreas, Mestl, Gerhard, Donabauer, Gabriele, Roehrer, Susanne
• Primary Examiner(s): Hailey, Patricia L
• Application Number:
  US14/673,569
• Publication Number:
  US 20150283538A1
• Time in Patent Office: 1,100 Days
• Field of Search: 502209, 502211, 502212, 549256, 549258, 549259, 549262
• CPC Class Codes: B01J 23/002 Mixed oxides other than spinels, e.g. perovskite
• CPC Class Codes: B01J 2523/00 Constitutive chemical elements of heterogeneous catalysts
• CPC Class Codes: B01J 2523/12 Sodium
• CPC Class Codes: B01J 2523/51 Phosphorus
• CPC Class Codes: B01J 2523/54 Bismuth
• CPC Class Codes: B01J 2523/55 Vanadium
• CPC Class Codes: B01J 2523/68 Molybdenum
• CPC Class Codes: B01J 27/198 Vanadium
• CPC Class Codes: B01J 27/199 with chromium, molybdenum, tungsten or polonium
• CPC Class Codes: B01J 37/0063 Granulating
• CPC Class Codes: B01J 37/10 in the presence of water, e.g. steam
• CPC Class Codes: B01J 37/28 Phosphorising
• CPC Class Codes: C07D 307/60 Two oxygen atoms, e.g. succinic anhydride

Abstract

The present invention relates to a catalyst containing a vanadium-phosphorus oxide and an alkali metal, wherein the proportion by weight of alkali metal in the vanadium-phosphorus oxide is in the range from 10 to 400 ppm, based on the total weight of the vanadium-phosphorus oxide, a process for producing it and also the use of the catalyst for the gas-phase oxidation of hydrocarbons, in particular for preparing maleic anhydride.

Claims

1. A catalyst comprising a vanadium-phosphorus oxide and an alkali metal selected from the group consisting of sodium, potassium and mixtures thereof, wherein the proportion by weight of alkali metal in the vanadium-phosphorus oxide is in the range from 10 to 400 ppm and wherein the vanadium-phosphorus oxide contains 0.10 to 0.90 w.t.-% molybdenum, based on the total weight of the vanadium-phosphorus oxide, respectively.

2. The catalyst as claimed in claim 1, wherein the proportion of alkali metal is in the range from 80 to 300 ppm.

3. The catalyst as claimed in claim 1, wherein the alkali metal is homogeneously distributed in the vanadium-phosphorus oxide.

4. The catalyst as claimed in claim 1, wherein the vanadium-phosphorus oxide is present as a mixed oxide of the alkali metal, vanadium and phosphorus.

5. The catalyst as claimed in claim 1, wherein the vanadium-phosphorus oxide is free of Zn and/or Ni.

7. A process for producing a catalyst as claimed in claim 1 comprising the step of reacting either a vanadium source and an alkali metal source or an alkali metal-containing vanadium source with a phosphorus source, wherein the alkali metal is selected from the group consisting of sodium, potassium and mixtures thereof, where the proportion of alkali metal is selected so that the vanadium-phosphorus oxide has a proportion by weight of alkali metal in the range from 10 to 400 ppm and wherein the vanadium-phosphorus oxide contains 0.10 to 0.90 w.t.-% molybdenum, based on the total weight of the vanadium-phosphorus oxide, respectively.

6. The catalyst as claimed in claim , wherein the catalyst consists of the vanadium-phosphorus oxide.

8. A catalyst for the gas-phase oxidation of a hydrocarbon comprising a vanadium-phosphorus oxide and an alkali metal, wherein the alkali metal is selected from the group consisting of sodium, potassium and mixtures thereof, wherein the proportion by weight of alkali metal in the vanadium-phosphorus oxide is in the range from 10 to 400 ppm and wherein the vanadium-phosphorus oxide contains 0.10 to 0.90 w.t.-% molybdenum, based on the total weight of the vanadium-phosphorus oxide, respectively.

9. The catalyst as claimed in claim 8, wherein the hydrocarbon is passed over the catalyst.

10. The catalyst as claimed in claim 8, wherein the hydrocarbon has at least 4 carbon atoms.

11. The catalyst as claimed in claim 8, wherein the hydrocarbon is n-butane.

12. The catalyst as claimed in claim 8, wherein maleic anhydride is formed in the (gas-phase) oxidation.