Metal matrix composite and method of forming

• US 9,945,012 B2
• Filed: 02/11/2014
• Issued: 04/17/2018
• Est. Priority Date: 02/11/2013
• Status: Active Grant

• Current Assignee: National Research Council Canada
• Original Assignee: National Research Council Canada
• Inventors: Bouchard, Dominique
• Primary Examiner(s): Wyszomierski, George
• Assistant Examiner(s): McGuthry Banks, Tima M
• Application Number:
  US14/767,170
• Publication Number:
  US 20150376745A1
• Time in Patent Office: 1,526 Days
• CPC Class Codes: B22D 19/14 the objects being filamentary or particulate in form making alloys containing fibres or filaments by contacting the fibres or filaments with molten metal C22C47/08
• CPC Class Codes: C22B 21/0084 melting and handling molten aluminium C22B21/02, C22B21/04 and C22B21/06 take precedence
• CPC Class Codes: C22B 21/06 refining electrolytic refining C25C; C22B21/0046, C22B21/0061 take precedence
• CPC Class Codes: C22B 21/062 using salt or fluxing agents C22B21/064, C22B21/066, and C22B21/068 take precedence
• CPC Class Codes: C22C 1/02 by melting C22C1/1036 takes precedence
• CPC Class Codes: C22C 1/026 Alloys based on aluminium
• CPC Class Codes: C22C 1/1036 starting from a melt
• CPC Class Codes: C22C 1/1047 by mixing and casting liquid metal matrix composites
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22C 21/00 Alloys based on aluminium
• CPC Class Codes: C22C 29/12 based on oxides
• CPC Class Codes: C22C 30/00 Alloys containing less than 50% by weight of each constituent
• CPC Class Codes: C22C 32/0031 Matrix based on refractory metals, W, Mo, Nb, Hf, Ta, Zr, Ti, V or alloys thereof
• CPC Class Codes: C22C 32/0036 Matrix based on Al, Mg, Be or alloys thereof
• CPC Class Codes: C22C 5/04 Alloys based on a platinum group metal

Abstract

Use of Ca in metal matrix composites (MMC) allows for incorporation of small and large amounts of ceramic (e.g. rutile TiO₂) into the metal (Al, or its alloys). Calcium remains principally out of the matrix and is part of a boundary layer system that has advantages for integrity of the MMC. Between 0.005 and 10 wt. % calcium (Ca) may be included, and more than 50 wt. % of rutile has been shown to be integrated. Rutile may therefore be used to reduce melt loss due to calcium from an aluminum or aluminum alloy melt.

Claims

1. A method for producing a metal matrix composite comprising:

stirring a reinforcement with an aluminum-containing molten or semisolid metal or alloy and between 0.005 and 10 wt. % calcium (Ca) to form a mixture, wherein the reinforcement is composed of particles each having a surface with a surface area bearing at least 20% of titanium oxide (TiO₂), and the TiO₂ is of crystal form other than anatase; and

cooling the mixture to produce a solid metal matrix composite to form a boundary material system between the crystals and the matrix, the boundary material system comprising calcium and aluminum oxides.

2. The method of claim 1 wherein the reinforcement is a cermet or ceramic powder including the TiO₂, or a compound coated with the TiO₂.

3. The method of claim 1 wherein the TiO₂ is in a rutile crystal form.

4. The method of claim 1 wherein at least 60 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

5. The method of claim 1 wherein the molten or semisolid metal is liquid aluminum with at least 80 wt. % or more of Al.

6. The method of claim 1 wherein the molten metal or alloy includes aluminum, and at least one alloying metal in liquid or semisolid form with the aluminum, the alloying metal being a metal other than magnesium.

7. The method of claim 1 wherein the particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

8. The method of claim 1 wherein the surfaces of the particles are flat or curved, smooth or rough, randomly textured or patterned, concave or convex, or any combination of the above.

9. The method of claim 1 wherein the particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

10. The method of claim 1 wherein each surface of the typical particle has a surface area with at least 20% of TiO₂.

11. The method of claim 10 wherein each surface of the typical particle bears at least 60% of TiO₂.

12. The method of claim 1 wherein cooling the mixture to produce a solid metal matrix composite comprises:

sandcasting, die casting, centrifugal casting, compocasting, thixocasting, rheocasting, thixomolding or other semisolid casting, pressure die casting, injection molding or extrusion.

13. The method of claim 1 wherein at least 80 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

14. The method of claim 1 wherein at least 97 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

15. The method of claim 1 wherein the calcium is added to the liquid or semisolid aluminum prior to introduction of the reinforcements.

16. The method of claim 1 wherein the calcium is added in an amount of 0.005 to 5 wt. %.

17. The method of claim 1 wherein the calcium is added in an amount of 0.01 to 2.5 wt. %.

18. A metal matrix composite (MMC) comprising:

a metal matrix of an aluminum or an alloy of aluminum; and

numerous sub-millimeter dimension embedded particles of a ceramic distributed throughout the metal matrix, the embedded particles comprising crystals of titanium oxide (TiO₂) in crystal form other than anatase,

wherein 0.005 to 10 wt. % calcium is present, and a boundary material system is formed between the crystals and the matrix, the boundary system comprising calcium and aluminum oxides.

19. The MMC of claim 18 wherein the calcium present is in an amount of 0.005 to 5 wt. %.

20. The MMC of claim 18 wherein the crystals are of rutile crystal form.

21. The MMC of claim 20 wherein the calcium is more highly concentrated within the boundary material system than within the embedded particles.

22. The MMC of claim 20 wherein the ceramic particles are composed of a ceramic oxide, boride, carbide, nitride or graphite coated with the rutile TiO₂.

23. The MMC of claim 20 wherein the ceramic particles are composed of an oxide or boride, or a ceramic that has a naturally formed oxidization layer coated with the rutile TiO₂.

24. The MMC of claim 18 wherein the calcium present is in an amount of 0.01 to 2.5 wt. %.

25. The MMC of claim 18 wherein the ceramic particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

26. The MMC of claim 18 wherein the ceramic particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

27. A method for reducing melt loss due to calcium defects in parts formed from an aluminum or aluminum alloy melt, the method comprising estimating a molar amount of calcium present, and adding at least an equal molar amount of rutile titania to the aluminum or aluminum alloy melt to form within the aluminum a boundary material system between crystals of the rutile titania and the aluminum, the boundary system comprising calcium and aluminum oxides.

28. A method for producing a metal matrix composite comprising:

at least partially melting an aluminum metal or alloy to form a molten or semisolid metal or alloy containing between 0.005 and 10 wt. % calcium (Ca);

stirring into the metal or alloy a reinforcement composed of particles of titanium oxide (TiO₂) of a crystal form other than anatase to form a mixture; and

cooling the mixture to produce a solid metal matrix composite forming a boundary material system between the crystals and the matrix, the boundary material system comprising calcium and aluminum oxides.

29. The method of claim 28 wherein the TiO₂ is in a rutile crystal form.

30. The method of claim 28 wherein at least 60 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

31. The method of claim 28 wherein at least 97 wt. % of the mixture comprises the reinforcement and molten metal or alloy.

32. The method of claim 28 wherein the molten or semisolid metal or alloy comprises at least 80 wt. % of liquid aluminum.

33. The method of claim 28 wherein the molten or semisolid metal or alloy includes aluminum, and at least one alloying metal in liquid or semisolid form with the aluminum, the one alloying metal being a metal other than magnesium.

34. The method of claim 28 wherein the particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

35. The method of claim 28 wherein the particles have surfaces that are:

flat or curved, smooth or rough, randomly textured or patterned, concave or convex, or any combination of the above.

36. The method of claim 28 wherein the particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

37. The method of claim 28 wherein cooling the mixture to produce a solid metal matrix composite comprises:

sandcasting, die casting, centrifugal casting, compocasting, thixocasting, rheocasting, thixomolding or other semisolid casting, pressure die casting, injection molding or extrusion.

38. The method of claim 28 wherein the calcium is added in an amount of 0.005 to 5 wt. %.

39. The method of claim 28 wherein the calcium is added in an amount of 0.01 to 2.5 wt. %.

40. A cast part comprising:

a metal matrix of an aluminum or an alloy of aluminum; and

numerous sub-millimeter dimension embedded particles of a ceramic distributed throughout the metal matrix, the embedded particles comprising crystals of titanium oxide (TiO₂) in crystal form other than anatase,

wherein 0.005 to 10 wt. % calcium is present, and a boundary material system is formed between the crystals and the matrix, the boundary system comprising calcium and aluminum oxides.

41. The cast part of claim 40 wherein the calcium is more highly concentrated within the boundary material system than within the embedded particles.

42. The cast part of claim 40 wherein the crystals are of rutile crystal form.

43. The cast part of claim 40 wherein the ceramic particles are composed of a ceramic oxide, boride, carbide, nitride or graphite coated with the rutile TiO₂.

44. The cast part of claim 40 wherein the ceramic particles are spherical, cubic, prismatic, polyhedral, angular, amorphous, elongated, rod-like, tubular, conic, fibrous, filamentary, platelet-like, disc-like, irregular, or any combination of the above.

45. The cast part of claim 40 wherein the ceramic particles have a predefined distribution of dimensions, with less than 10% of the powders having dimensions greater than a maximum dimension, which is less than 1 cm, and with less than 10% of the powders having dimensions smaller than a minimum dimension, which is greater than 10 nm.

46. The cast part of claim 40 wherein the calcium present is in an amount of 0.005 to 5 wt. %.

47. The cast part of claim 40 wherein the calcium present is in an amount of 0.01 to 2.5 wt. %.