Carboxylic acid-modified nitrile-based copolymer latex composition and dip molded article including the same

• US 9,969,861 B2
• Filed: 08/29/2014
• Issued: 05/15/2018
• Est. Priority Date: 08/29/2013
• Status: Active Grant

• Current Assignee: LG Chem Limited (LG Corporation)
• Original Assignee: LG Chem Limited (LG Corporation)
• Inventors: Cha, Yu Jin, Kim, Jung Eun, Kim, Hyun Woo, Kim, Ji Hyun
• Primary Examiner(s): Reddy, Karuna P
• Application Number:
  US14/429,665
• Publication Number:
  US 20150232637A1
• Time in Patent Office: 1,355 Days
• CPC Class Codes: C08J 2309/04 Latex
• CPC Class Codes: C08J 5/02 Direct processing of dispersions, e.g. latex, to articles
• CPC Class Codes: C08K 3/346 Clay
• CPC Class Codes: C08L 13/02 Latex

Abstract

The present invention relates to a carboxylic acid-modified nitrile-based copolymer latex composition and a dip molded article including the same, the composition including: a carboxylic acid-modified nitrile-based copolymer latex having a glass transition temperature of −30 to −20° C.; and a bentonite dispersion solution. The dip molded article using the carboxylic acid-modified nitrile-based copolymer latex composition according to the present invention has high tensile strength and excellent wearable sensation, and thus the dip molded article may be usefully applied to dip molded latex articles such as surgical gloves, checkup gloves, a condom, a catheter, industrial gloves, household gloves, or health care articles.

Claims

1. A carboxylic acid-modified nitrile-based copolymer latex composition comprising:

a carboxylic acid-modified nitrile-based copolymer latex having a glass transition temperature of −

30 to −

20°

C.; and

a bentonite dispersion solution,

wherein the carboxylic acid-modified nitrile-based copolymer latex is formed by polymerizing a monomer mixture including 62.2 to 70 wt % of 1,3 butadiene, 25 to 31.4 wt % of acrylonitrile, and 5 to 6.8 wt % of methacrylic acid based on a total weight of monomers constituting the carboxylic acid-modified nitrile-based copolymer,

wherein the carboxylic acid-modified nitrile-based copolymer latex and the bentonite dispersion solution are included at a weight ratio of 99;

1 to 95;

5,

wherein in the bentonite dispersion solution, 1 to 8 parts by weight of bentonite is dispersed based on 100 parts by weight of a solution, and

wherein bentonite is present in an amount ranging from 0.022 to 0.87 parts by weight based on 100 parts by weight of dried carboxylic acid-modified nitrile-based copolymer latex.

2. The composition of claim 1, wherein the carboxylic acid-modified nitrile-based copolymer latex has an average particle diameter of 100 nm or more and 200 nm or less.

3. The composition of claim 1, wherein the bentonite dispersion solution includes bentonite having an average particle diameter of 500 nm or more.

4. The composition of claim 1, further comprising:

one or more additives selected from the group consisting of a vulcanizing agent, an ionic cross-linking agent, a pigment, a thickener, and a pH adjuster.

5. The composition of claim 1, wherein bentonite is present in an amount ranging from 0.022 to 0.17 parts by weight based on 100 parts by weight of dried carboxylic acid-modified nitrile-based copolymer latex.

6. A dip molded article comprising the carboxylic acid-modified nitrile-based copolymer latex composition according to claim 1.

7. The dip molded article of claim 6, wherein the dip molded article is a dip molded latex article such as surgical gloves, checkup gloves, a condom, a catheter, industrial gloves, household gloves, or health care articles.