Reinforced superconducting wire and method for manufacturing the same

• US 9,972,423 B2
• Filed: 06/10/2014
• Issued: 05/15/2018
• Est. Priority Date: 06/19/2013
• Status: Active Grant

• Current Assignee: Solid Material Solutions, LLC, Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Original Assignee: Solid Material Solutions, LLC, Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Inventors: Otto, Alexander, Yamazaki, Kouhei
• Primary Examiner(s): WARTALOWICZ, PAUL A
• Application Number:
  US14/898,302
• Publication Number:
  US 20160141080A1
• Time in Patent Office: 1,435 Days
• Field of Search: 505239
• CPC Class Codes: C22C 30/00 Alloys containing less than 50% by weight of each constituent
• CPC Class Codes: H01B 12/06 Films or wires on bases or cores
• CPC Class Codes: H10N 60/0576 characterised by the substrate
• CPC Class Codes: H10N 60/0801 Processes peculiar to the manufacture or treatment of filaments or composite wires
• CPC Class Codes: H10N 60/203 comprising high-Tc ceramic materials

Abstract

Reinforced materials for high temperature superconducting tape. More specifically reinforcement materials for significantly reducing the amount of required reinforcement and attaining much higher stress tolerances at practical conductor dimensions are described herein.

Claims

1. A reinforced superconducting wire, comprising:

a superconducting tape portion, said superconducting tape portion being in a state of compressive residual stress; and

a reinforcement member connected to said superconducting tape portion, wherein

a material forming said reinforcement member includes nickel, cobalt and chromium, and

in said material forming said reinforcement member,

said nickel is in a range from 20 wt % or more to 42 wt % or less,

said cobalt is in a range from 23 wt % or more to 44 wt % or less, and

said chromium is in a range from 14 wt % or more to 26 wt % or less.

2. The reinforced superconducting wire according to claim 1, wherein said reinforcement member is coated with a surface material layer.

3. The reinforced superconducting wire according to claim 2, wherein said surface material layer includes at least one metal selected from the group consisting of copper, tin, gold, silver, platinum group metals, gallium, and indium.

4. The reinforced superconducting wire according to claim 1, wherein said nickel is in a range from 25 wt % or more to 37 wt % or less.

5. The reinforced superconducting wire according to claim 1, wherein said cobalt is in a range from 28 wt % or more to 39 wt % or less.

6. The reinforced superconducting wire according to claim 1, wherein said chromium is in a range from 19 wt % or more to 21 wt % or less.

7. The reinforced superconducting wire according to claim 1, wherein said material forming said reinforcement member further includes titanium.

8. The reinforced superconducting wire according to claim 1, wherein said reinforcement member is such that a characteristic value FOM defined in accordance with the following equation exceeds 1050% GPa/K:

FOM=CTE×

Proportionality Limit Strain×

Modulus all in the 273K to 323K temperature range, and where CTE is in PPM m/m/K, Elastic Modulus is in GPa and Proportionality Limit is in percent.

9. The reinforced superconducting wire according to claim 1, wherein a rate of decrease in a critical current value when a tensile stress of 400 MPa is applied, to a critical current value when a tensile stress is not applied is 5% or less.

10. The reinforced superconducting wire according to claim 1, wherein said reinforcement member is in tension and applies the compressive residual stress to said superconducting tape core.

11. The reinforced superconducting wire according to claim 1, wherein said reinforcement member is in tension and generates a tensile strain within a range of 0.25% to 0.8% in the reinforced superconducting wire.

12. The reinforced superconducting wire according to claim 1, wherein said reinforcement member is in tension within a range of 25 N to 230 N.

13. The reinforced superconducting wire according to claim 1, wherein said reinforcement member is in tension within a range of 100 N to 230 N.

14. A reinforced high temperature superconductor comprised of a) a BSCCO 2223/silver tape core in a state of compressive residual stress, b) two reinforcement strips, one on each side of the broad surfaces of the tape c) a joining material comprised primarily of an organic adhesive or solder containing in excess of 5% of any one of Sn, Pb, In, Sb or Bi between the reinforcement strips and BSCCO 2223/silver tape core, coating the outside of the assembly and between the reinforcement strips at the edges of the assembly such that the reinforcement occupies less than 35% of the total composite cross sectional area and where the critical current of the composite is not degraded by more than 5% with an applied tensile stress in excess of 400 MPa at a temperature of 300 K or lower.