Visibly transparent, luminescent solar concentrator

• US 9,985,158 B2
• Filed: 06/13/2012
• Issued: 05/29/2018
• Est. Priority Date: 06/13/2012
• Status: Active Grant

• Current Assignee: Massachusetts Institute of Technology
• Original Assignee: Massachusetts Institute of Technology
• Inventors: Lunt, Richard Royal, Bulovic, Vladimir, Barr, Miles Clark
• Primary Examiner(s): Slawski, Magali P
• Application Number:
  US13/495,379
• Publication Number:
  US 20130333755A1
• Time in Patent Office: 2,176 Days
• Field of Search: None
• CPC Class Codes: H01L 31/055 where light is absorbed and re-emitted at a different wavelength by the optical element directly associated or integrated with the PV cell, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
• CPC Class Codes: Y02E 10/52 PV systems with concentrators

Abstract

A visibly transparent luminescent solar concentrator (LSC) is disclosed. The LSC includes a transparent substrate having at least one edge surface. A dye layer is coupled to the substrate, the dye layer having a peak absorption wavelength outside the visible band, the dye layer being configured to re-emit light at a peak emission wavelength outside the visible band, at least a portion of the re-emitted light being waveguided to the edge surface of the substrate. A photovoltaic device is coupled to the edge surface of the transparent substrate, the photovoltaic device being configured to absorb light at the peak emission wavelength and generate electrical energy.

Claims

1. A visibly transparent luminescent solar concentrator (LSC) having an average visible band absorption of up to 20%, the LSC comprising:

a visibly transparent substrate having at least one edge surface, wherein the visibly transparent substrate has an average visible band transmission of 45% or more;

visibly transparent photoluminescent organic dye molecules, corresponding to luminophore components, coupled to the visibly transparent substrate, wherein the visibly transparent photoluminescent organic dye molecules;

exhibit a peak absorption wavelength outside a visible band,

exhibit a maximum visible band absorption of up to 20%, and

absorb light at wavelengths outside the visible band and generate photoluminescent light at a peak emission wavelength outside the visible band,

wherein the visibly transparent substrate is configured to waveguide at least a portion of the photoluminescent light to the at least one edge surface of the visibly transparent substrate; and

a photovoltaic device coupled to the at least one edge surface of the visibly transparent substrate, wherein the photovoltaic device is configured to absorb light at the peak emission wavelength outside the visible band and generate electrical energy.

2. The LSC of claim 1, wherein the peak emission wavelength outside the visible band is selected to optimize internal reflections of the photoluminescent light within the visibly transparent substrate.

3. The LSC of claim 1, wherein the visibly transparent substrate has an index of refraction selected to optimize internal reflections of the photoluminescent light within the visibly transparent substrate.

4. The LSC of claim 1, wherein the peak absorption wavelength outside the visible band is in at least one of an ultraviolet (UV) band and a near-infrared (NIR) band.

5. The LSC of claim 1, wherein the peak emission wavelength outside the visible band is in a near-infrared (NIR) band.

6. The LSC of claim 1, wherein the visibly transparent photoluminescent organic molecules comprise a molecular dye or an organometallic complex.

7. The LSC of claim 1, wherein the visibly transparent photoluminescent organic molecules comprise at least one component selected from the group consisting of a phthalocyanine, a porphyrin, a rhodamine, an organic laser dye, a perylene, a cyanine, a coumarin, a dioxazine, a naphthalimide, a thiazine, and a stilbene.

8. The LSC of claim 1, wherein the visibly transparent photoluminescent organic molecules comprise at least one of U3, SnPc, and single-wall carbon nanotubes.

9. The LSC of claim 1, further comprising second visibly transparent photoluminescent organic molecules coupled to the visibly transparent substrate, wherein the second visibly transparent photoluminescent organic molecules exhibit a second maximum visible band absorption of up to 20%.

10. The LSC of claim 1, further comprising second visibly transparent photoluminescent organic molecules coupled to the visibly transparent substrate, wherein the second visibly transparent photoluminescent organic molecules exhibit a second maximum visible band absorption of up to 50%.

11. The LSC of claim 1, further comprising an index matching layer disposed between the at least one edge surface of the visibly transparent substrate and the photovoltaic device.

12. The LSC of claim 1 wherein the photovoltaic device comprises at least one of cadmium telluride, cadmium indium gallium selenide, copper indium sulfide, amorphous silicon, monocrystalline silicon, multicrystalline silicon, amorphous silicon/polysilicon micromorph, cadmium selenide, aluminum antimonide, indium phosphide, aluminum arsenide, gallium phosphide, and gallium antimonide, gallium arsenide, gallium indium phosphide, germanium, an inorganic nanocrystal and an organic semiconductor.

13. The LSC of claim 1, further comprising a wavelength selective mirror coupled to the visibly transparent substrate, wherein the wavelength selective mirror reflects light at the peak emission wavelength outside the visible band.

14. The LSC of claim 13, wherein the wavelength selective mirror transmits incident light having wavelengths in the visible band and at the peak absorption wavelength outside the visible band.

15. The LSC of claim 1, further comprising a first wavelength selective mirror disposed on a first surface of the visibly transparent substrate and a second wavelength selective mirror disposed on a second surface of the visibly transparent substrate, wherein the first wavelength selective mirror is transparent in the visible band and at the peak absorption wavelength outside the visible band and reflective at the peak emission wavelength outside the visible band, and wherein the second wavelength selective mirror is transparent in the visible band and reflective at both the peak emission wavelength outside the visible band and at the peak absorption wavelength outside the visible band.

33. The LSC of claim 1, wherein the substrate includes an upper surface and a lower surface, and wherein the visibly transparent photoluminescent organic molecules are included in a layer coupled to the upper surface, a layer coupled to the lower surface, or layers coupled to both the upper surface and the lower surface.

34. The LSC of claim 1, wherein the visibly transparent photoluminescent organic molecules are distributed throughout a thickness of the substrate.

16. A method of forming a visibly transparent luminescent solar concentrator (LSC) having an average visible band absorption of up to 20%, the method comprising:

providing a visibly transparent substrate having at least one edge surface, wherein the visibly transparent substrate has an average visible band transmission of 45% or more;

coupling visibly transparent photoluminescent organic molecules, corresponding to luminophore components, to the visibly transparent substrate, wherein the visibly transparent photoluminescent organic molecules;

exhibit a peak absorption wavelength outside a visible band,

exhibit a maximum visible band absorption of up to 20%, and

absorb light at wavelengths outside the visible band and generate photoluminescent light at a peak emission wavelength outside the visible band, and

wherein the visibly transparent substrate is configured to waveguide at least a portion of the photoluminescent light to the at least one edge surface of the visibly transparent substrate, the visibly transparent LSC having up to 20% light absorption across the visible band; and

coupling a photovoltaic device to the at least one edge surface of the visibly transparent substrate, wherein the photovoltaic device is configured to absorb light at the peak emission wavelength outside the visible band and generate electrical energy.

17. The method of claim 16, wherein the peak emission wavelength outside the visible band is selected to optimize internal reflections within the visibly transparent substrate.

18. The method of claim 16, wherein the visibly transparent substrate has an index of refraction selected to optimize internal reflections within the visibly transparent substrate.

19. The method of claim 16, wherein the peak absorption wavelength outside the visible band is in at least one of an ultraviolet (UV) band and a near-infrared (NIR) band.

20. The method of claim 16, wherein the peak emission wavelength outside the visible band is in a near-infrared (NIR) band.

21. The method of claim 16, wherein the visibly transparent photoluminescent organic molecules exhibit a band gap between an emission band including the peak emission wavelength outside the visible band and an absorption band including the peak absorption wavelength outside the visible band.

22. The method of claim 16, wherein the visibly transparent photoluminescent organic molecules comprise of a molecular dye or an organometallic complex.

23. The method of claim 16, wherein the visibly transparent photoluminescent organic molecules comprise at least one component selected from the group consisting of a phthalocyanine, a porphyrin, a rhodamine, an organic laser dye, a perylene, a cyanine, a coumarin, a dioxazine, a naphthalimide, a thiazine, and a stilbene.

24. The method of claim 16, wherein the visibly transparent photoluminescent organic molecules comprise at least one of U3, SnPc, and single-wall carbon nanotubes.

25. The method of claim 16, further comprising coupling second visibly transparent photoluminescent organic molecules to the visibly transparent substrate, wherein the second visibly transparent photoluminescent organic molecules exhibit a second maximum visible band absorption of up to 20%.

26. The method of claim 16, further comprising coupling second visibly transparent photoluminescent organic molecules to the visibly transparent substrate, wherein the second visibly transparent photoluminescent organic molecules exhibit a second maximum visible band absorption of up to 50%.

27. The method of claim 16, further comprising disposing an index matching layer between the at least one edge surface of the visibly transparent substrate and the photovoltaic device.

28. The method of claim 16, further comprising disposing a wavelength selective mirror on the visibly transparent substrate, wherein the wavelength selective mirror reflects light at the peak emission wavelength outside the visible band.

29. The method of claim 28, wherein the wavelength selective mirror transmits incident light having wavelengths in the visible band and at the peak absorption wavelength outside the visible band.

30. The method of claim 16, further comprising disposing a first wavelength selective mirror on a first surface of the visibly transparent substrate and disposing a second wavelength selective mirror on a second surface of the visibly transparent substrate, wherein the first wavelength selective mirror is transparent in the visible band and at the peak absorption wavelength outside the visible band and reflective at the peak emission wavelength, and wherein the second wavelength selective mirror is transparent in the visible band and reflective at both the peak emission wavelength outside the visible band and at the peak absorption wavelength outside the visible band.

31. The method of claim 16 wherein the photovoltaic device comprises at least one of cadmium telluride, cadmium indium gallium selenide, copper indium sulfide, amorphous silicon, monocrystalline silicon, multicrystalline silicon, amorphous silicon/polysilicon micromorph, cadmium selenide, aluminum antimonide, indium phosphide, aluminum arsenide, gallium phosphide, and gallium antimonide, gallium arsenide, gallium indium phosphide, germanium, an inorganic nanocrystal and an organic semiconductor.

32. A method of generating electricity, the method comprising:

providing a visibly transparent luminescent solar concentrator (LSC) having an average visible band absorption of up to 20%, wherein the LSC includes;

a visibly transparent substrate having at least one edge surface, wherein the visibly transparent substrate has an average visible band transmission of 45% or more;

visibly transparent photoluminescent organic molecules, corresponding to luminophore components, coupled to the visibly transparent substrate, wherein the visibly transparent photoluminescent organic molecules;

exhibit a peak absorption wavelength outside a visible band,

exhibit a maximum visible band absorption of up to 20%, and

absorb light at wavelengths outside the visible band and generate photoluminescent light at a peak emission wavelength outside the visible band,

wherein the visibly transparent substrate is configured to waveguide at least a portion of the photoluminescent light to the at least one edge surface of the visibly transparent substrate; and

a photovoltaic device coupled to the at least one edge surface of the visibly transparent substrate, wherein the photovoltaic device is configured to absorb light at the peak emission wavelength outside the visible band and generate electrical energy; and

exposing the LSC to incident light having wavelengths outside the visible band, wherein at least a portion of the incident light is absorbed by the visibly transparent photoluminescent organic molecules, wherein the visibly transparent photoluminescent organic molecules generate photoluminescent light having wavelengths outside the visible band, wherein at least a portion of the photoluminescent light having wavelengths outside the visible band is waveguided within the visibly transparent substrate to the photovoltaic device, and wherein the photovoltaic device absorbs at least a portion of the waveguided photoluminescent light having wavelengths outside the visible band to generate electricity.