Flow-through oxygenator

• US RE45,415 E1
• Filed: 09/28/2011
• Issued: 03/17/2015
• Est. Priority Date: 02/22/2002
• Status: Expired

• Current Assignee: Oxygenator Water Technologies, Inc.
• Original Assignee: Oxygenator Water Technologies, Inc.
• Inventors: Senkiw, James Andrew
• Primary Examiner(s): Griffin, Walter D
• Assistant Examiner(s): Allen, Cameron J
• Application Number:
  US13/247,241
• Time in Patent Office: 1,266 Days
• Field of Search: 210/739, 210/746, 210/748.01, 210/748.16, 210/748.15, 210/748.17, 210/748.19, 210/749, 210/757, 210/167.21, 422/22, 422/27, 422/28, 422/129, 422/186, 422/186.04, 422/186.03, 422/186.07, 422/186.01, 422/186.1, 422/186.15, 422/186.16, 422/186.21, 422/616, 422/243, 422/305, 422/308, 204/155, 204/157.15, 204/157.5, 204/164, 204/176, 204/178, 204/450, 204/554, 204/193, 204/194, 204/260, 204/272, 204/280, 204/277, 204/278.5, 204/287, 204/288, 204/288.1, 204/288.2, 204/230.2, 205/701, 205/628, 205/633, 205/742, 205/756, 205/757, 221/92, 223/217, 22/1, 119/263
• US Class Current: 210/739
• CPC Class Codes: A01G 31/00 Soilless cultivation, e.g. hydroponics growth substrates therefor A01G24/00; cultivation of seaweed A01G33/00
• CPC Class Codes: A01G 31/02 Special apparatus therefor self-acting watering devices A01G27/00
• CPC Class Codes: A01K 63/042 Introducing gases into the water, e.g. aerators, air pumps
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C02F 1/4672 by electrooxydation
• CPC Class Codes: C02F 1/68 by addition of specified substances, e.g. trace elements, for ameliorating potable water medicinal water A61K
• CPC Class Codes: C02F 1/727 using pure oxygen or oxygen rich gas
• CPC Class Codes: C02F 2001/46133 characterised by the material
• CPC Class Codes: C02F 2001/46138 Electrodes comprising a substrate and a coating
• CPC Class Codes: C02F 2001/46157 Perforated or foraminous electrodes
• CPC Class Codes: C02F 2201/4612 Controlling or monitoring
• CPC Class Codes: C02F 2201/4615 Time
• CPC Class Codes: C02F 2209/02 Temperature
• CPC Class Codes: C02F 3/26 using pure oxygen or oxygen-rich gas
• CPC Class Codes: C02F 7/00 Aeration of stretches of water
• CPC Class Codes: Y02E 60/366 by electrolysis of water
• CPC Class Codes: Y02P 60/216 Aquaponics or hydroponics
• CPC Class Codes: Y02W 10/15 Aerobic processes

Abstract

An oxygen emitter which is an electrolytic cell is disclosed. When the anode and cathode are separated by a critical distance, very small microbubbles and nanobubbles of oxygen are generated. The very small oxygen bubbles remain in suspension, forming a solution supersaturated in oxygen. A flow-through model for oxygenating flowing water is disclosed. The use of supersaturated water for enhancing the growth of plants is disclosed. Methods for applying supersaturated water to plants manually, by drip irrigation or in hydroponic culture are described. The treatment of waste water by raising the dissolved oxygen with the use of an oxygen emitter is disclosed.

Claims

1. A method for treating waste water comprising;

providing a flow-through oxygenator comprising an emitter for electrolytic generation of microbubbles of oxygen comprising an anode separated at a critical distance from a cathode and a power source all in electrical communication with each other,

placing the emitter within a conduit; and

passing waste water through the conduit.

2. An emitter for electrolytic generation of microbubbles of oxygen in an aqueous medium comprising:

an anode separated at a critical distance from a cathode, a nonconductive spacer maintaining the separation of the anode and cathode, the nonconductive spacer having a spacer thickness between 0.005 to 0.050 inches such that the critical distance is less than 0.060 inches and a power source all in electrical communication with each other, wherein the critical distance results in the formation of oxygen bubbles having a bubble diameter less than 0.0006 inches, said oxygen bubbles being incapable of breaking the surface tension of the aqueous medium such that said aqueous medium is supersaturated with oxygen.

3. The emitter of claim 2, wherein the anode is a metal or a metallic oxide or a combination of a metal and a metallic oxide.

4. The emitter of claim 2, wherein the anode is platinum and iridium oxide on a support.

5. The emitter of claim 2, wherein the cathode is a metal or metallic oxide or a combination of a metal and a metallic oxide.

6. The emitter of claim 2, wherein the critical distance is 0.005 to 0.060 inches.

7. The emitter of claim 2, comprising a plurality of anodes separated at the critical distance from a plurality of cathodes.

8. A method for oxygenating a non-native habitat for temporarily keeping aquatic animals, comprising:

inserting the emitter of claim 2 into the aqueous medium, the non-native habitat comprising an aquarium, a bait bucket or a live well.

9. A method for lowering the biologic oxygen demand of polluted water comprising:

passing the polluted water through a vessel containing the emitter of claim 2.

10. A supersaturated aqueous product formed with the emitter of claim 2, the supersaturated aqueous product having an approximately neutral pH.

11. The emitter of claim 2, further comprising a timer control.

12. The emitter of claim 2, wherein the anode and cathode are arranged such that the emitter assumes a funnel or pyramidal shaped emitter.

13. A method for producing an oxygenated aqueous composition comprising:

flowing water at a flow rate no greater than 12 gallons per minute through an electrolysis emitter comprising an electrical power source electrically connected to an anode electrode and a cathode electrode contained in a tubular housing,

causing electricity to flow from the power source to the electrodes, and,

producing the composition comprising a suspension comprising oxygen microbubbles and nanobubbles in the water, the microbubbles and nanobubbles having a bubble diameter of less than 50 microns, wherein;

the anode electrode is separated at a critical distance from the cathode such that the critical distance is from 0.005 inches to 0.140 inches;

the power source produces a voltage no greater than about 28.3 volts and an amperage no greater than about 13 amps,

the tubular housing has an inlet and an outlet and a tubular flow axis from the inlet to the outlet;

the water flows in the inlet, out the outlet, is in fluid connection with the electrodes, and the water flowing into the inlet has a conductivity produced by the presence of dissolved solids such that the water supports plant or animal life.

14. A method according to claim 13 wherein the housing contains at least one anode and at least one cathode, the electrodes are of a grid or solid design and are relatively positioned in cross section along the radius of the tubular housing with their long axes substantially parallel to the tubular water flow axis of the housing.

15. A method according to claim 13 wherein the housing has a side arm positioned at an angle relative to the tubular flow axis and the electrodes are located in the side arm.

16. A method according to claim 15 wherein the side arm contains a multiple number of anode and cathode electrodes and the electrodes are plate shaped.

17. A method according to claim 14 wherein a multiple number of anode and cathodes are present and are of grid or solid design.

18. A method according to claim 13 wherein the water has a temperature no greater than about ambient temperature at the inlet and the water temperature is a factor for formation of the suspension.

19. A method according to claim 13 wherein the microbubbles and nanobubbles remain in the water at least in part for a period up to several hours.

20. A method according to claim 19 wherein the period for which the microbubbles and nanobubbles at least in part remain in the water is determined by containing the water with microbubbles and nanobubbles in a two and one half gallon aquarium reservoir container.

21. A method according to claim 13 wherein the microbubbles and nanobubbles supersaturate the water.

22. A method according to claim 13 wherein the bubble diameter of the microbubbles and nanobubbles is less than 0.0006 inches.

23. A method according to claim 13 wherein the separation of electrodes is maintained by a nonconductive spacer.

24. A method according to claim 13 wherein the electrode separation distance is about 0.045 to about 0.06 inches.

25. A method according to claim 13 wherein the microbubbles and nanobubbles are substantially incapable of breaking the surface tension of the water.

26. A method according to claim 13 wherein each anode and cathode electrode of the emitter is positioned so that substantially all points midway between opposing anode and cathode electrodes are closer to a surface of the tubular housing than to a center point within the tubular housing.

27. A method according to claim 26 wherein each anode and cathode electrode of the emitter are positioned so that the electrodes do not obstruct a water flow passage along the center of the tubular housing.