A curable epoxy resin composition and laminates made therefrom

A curable epoxy resin composition and laminates made therefrom

  • CN 101,341,181 B
  • Filed: 12/20/2006
  • Issued: 09/04/2013
  • Est. Priority Date: 12/22/2005
  • Status: Active Grant
First Claim
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1. curable halogen-containing composition epoxy resin, it comprises:

  • (a) at least a Resins, epoxy, wherein said Resins, epoxy Shi oxazolidone modified epoxy;

    (b) at least a stiffening agent;

    Wherein stiffening agent is that the compound of phenolic hydroxy group functionality maybe can be by adding the compound of thermogenesis phenolic hydroxyl group functionality;

    (c) the nitrogenous catalyzer of catalytic amount;

    With(d) can reduce the non-nitrogenous catalyzer auxiliary compound of nitrogenous catalyst concn, described catalyzer auxiliary is carboxylic acid, carboxylic acid anhydride or its mixture;

    Wherein, said components (a)-(d) at least a or multiple is halogenation or halogen-containing;

    If perhaps said components does not all have halogenation, then wherein resin combination comprises (e) halogenation or halogen-containing flame retardant compound;

    Be characterised in that the stroke cure gelation time of resin combination maintains 90 seconds to 600 seconds when when measuring down for 170 ℃

    ;

    And make the gained cured product that forms by the cure curable composition epoxy resin contain the following character that is in admirable proportion;

    (1) greater than 130 ℃

    Tg;

    (2) greater than 320 ℃

    Td, the degradation temperature of described Td for recording according to IPC-TM-650-2.3.40, and with 10 ℃

    /minute determination of heating rate Td;

    (3) greater than 1 minute T288, the leafing time 288 ℃

    under of described T288 for recording according to IPC-TM-650-2.4.24.1;

    (4) greater than the bounding force to copper of 10N/cm, the described copper-stripping intensity of bounding force for recording according to IPC-TM-650-2.4.8C to copper;

    With(5) the UL94 flame retardant resistance of V-1 grading at least.

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