A kind of phase transfer catalyst that is used for oxidation reaction and preparation method thereof and application

A kind of phase transfer catalyst that is used for oxidation reaction and preparation method thereof and application

  • CN 101,590,431 A
  • Filed: 07/17/2009
  • Published: 12/02/2009
  • Est. Priority Date: 08/08/2008
  • Status: Active Application
First Claim
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1. a reaction control phase transfer catalyst that is used for oxidation reaction is characterized in that, is heteropoly acid organic salt AmB3-mXMnNk-nO4+3k, in the described structure expression:

  • ---A, B are cationic moieties, and with [R1R2R3R4N+] expression, wherein R1, R2, R3, R4 are alkyl, cycloalkyl or the benzyls of H-, straight or branched;

    Represent with R1R2R3N that perhaps R1R2R3N is pyridine or its homologue;

    ---X is a hetero atom, is phosphorus or arsenic;

    ---M is a tungsten atom, and N is a molybdenum atom;





    m=

    1,

    2,

    3;

    k=

    3,

    4,

    5,

    6;

    0≤

    n≤

    k;

    N=0 or k do not set up simultaneously with m=3.

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