It is used to prepare the ingredient of solid catalyst of olefin polymer

It is used to prepare the ingredient of solid catalyst of olefin polymer

  • CN 104,177,520 B
  • Filed: 05/21/2013
  • Issued: 06/12/2018
  • Est. Priority Date: 05/21/2013
  • Status: Active Grant
First Claim
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1. a kind of ingredient of solid catalyst for olefinic polyreaction, described to give it includes magnesium, titanium, halogen and electron donorElectron is selected from least one of following glycol ester compounds:

  • 2,4- hexylene glycols two (4- propylbenzoic acids ester), 2,4- oneself twoAlcohol two (4- butylbenzoic acids ester), 2,4- hexylene glycols two (4- isobutyl-benzenes formic acid esters), (the 4- tert-butyl benzene first of 2,4- hexylene glycols twoAcid esters), 3- methyl -2,4- hexylene glycols two (4- propylbenzoic acids ester), two (4- butylbenzoic acids of 3- methyl -2,4- hexylene glycolsEster), 3- methyl -2,4- hexylene glycols two (4- isobutyl-benzenes formic acid esters), two (4- p t butylbenzoic acids of 3- methyl -2,4- hexylene glycolsEster), 3- ethyl -2,4- hexylene glycols two (4- propylbenzoic acids ester), 3- ethyl -2,4- hexylene glycols two (4- butylbenzoic acids ester),3- ethyl -2,4- hexylene glycols two (4- isobutyl-benzenes formic acid esters), 3- ethyl -2,4- hexylene glycols two (4- p t butylbenzoic acids ester),3,5- heptandiols two (4- propylbenzoic acids ester), 3,5- heptandiols two (4- isopropyl acids ester), (the 4- fourths of 3,5- heptandiols twoYl benzoic acid ester), 3,5- heptandiols two (4- isobutyl-benzenes formic acid esters), 3,5- heptandiols two (4- p t butylbenzoic acids ester), 3,5- heptandiols-cinnamic acid -4- propylbenzoic acids ester, 4- methyl -3,5- heptandiols two (4- propylbenzoic acids ester), 4- methyl -3,5- heptandiols two (4- isopropyl acids ester), 4- methyl -3,5- heptandiols two (4- butylbenzoic acids ester), 4- methyl -3,5-Heptandiol two (4- isobutyl-benzenes formic acid esters), 4- methyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 4- ethyls -3,5-Heptandiol two (4- propylbenzoic acids ester), 4- ethyl -3,5- heptandiols two (4- isopropyl acids ester), 4- ethyls -3,5- heptanGlycol two (4- butylbenzoic acids ester), 4- ethyl -3,5- heptandiols two (4- isobutyl-benzenes formic acid esters), 4- ethyls -3,5- heptan twoAlcohol two (4- p t butylbenzoic acids ester), 4- propyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 4- butyl -3,5- heptan twoAlcohol two (4- p t butylbenzoic acids ester), 2,4- dimethyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 2,6- dimethyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 4,4- dimethyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 2,2-Dimethyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), two (4- butylbenzoic acids of 2- methyl -4- ethyl -3,5- heptandiolsEster), 4- methyl -4- ethyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 2- methyl -4- propyl -3,5- heptandiols two(4- p t butylbenzoic acids ester), 3- methyl -3- propyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 4- methyl -4- thirdBase -3,5- heptandiols two (4- p t butylbenzoic acids ester), 3- methyl -2,4- heptandiols two (4- propylbenzoic acids ester), 3- methyl -2,4- heptandiols two (3- propylbenzoic acids ester), 3,6- dimethyl -2,4- heptandiols two (4- p t butylbenzoic acids ester), 2,2,6,6- tetramethyl -3,5- heptandiols two (4- p t butylbenzoic acids ester), 4- methyl -3,5- ethohexadiols two (4- butylbenzoic acids ester),4- ethyl -3,5- ethohexadiols two (4- p t butylbenzoic acids ester), 4- propyl -3,5- ethohexadiols two (4- p t butylbenzoic acids ester),4- butyl -3,5- ethohexadiols two (4- p t butylbenzoic acids ester), two (4- butylbenzoic acids of 4,4- dimethyl -3,5- ethohexadiolsEster), 4,4- diethyl -3,5- ethohexadiols two (4- propylbenzoic acids ester), two (4- tertiary butyls of 4,4- dipropyl -3,5- ethohexadiolsBenzoic ether), 4- methyl -4- ethyl -3,5- ethohexadiols two (4- second butylbenzoic acids ester), 2- methyl -4- ethyls -3,5- pungent twoAlcohol two (4- p t butylbenzoic acids ester), 2- methyl -6- ethyl -3,5- ethohexadiols two (4- p t butylbenzoic acids ester), 4,6- nonyls twoAlcohol two (4- propylbenzoic acids ester), 4,6- nonanediols two (4- butylbenzoic acids ester), (the 4- isobutyl-benzene formic acid of 4,6- nonanediols twoEster), 4,6- nonanediols two (4- p t butylbenzoic acids ester), 5- methyl -4,6- nonanediols two (4- propylbenzoic acids ester), 5- firstBase -4,6- nonanediols two (4- butylbenzoic acids ester), 5- methyl -4,6- nonanediols two (4- isobutyl-benzenes formic acid esters), 5- methyl -4,6- nonanediols two (4- p t butylbenzoic acids ester), 5- ethyl -4,6- nonanediols two (4- propylbenzoic acids ester), 5- ethyl -4,6- nonanediols two (4- butylbenzoic acids ester), 5- ethyl -4,6- nonanediols two (4- isobutyl-benzenes formic acid esters), 4,6- nonanediols two(4- p t butylbenzoic acids ester), 5- propyl -4,6- nonanediols two (4- p t butylbenzoic acids ester), 5- butyl -4,6- nonanediols two(4- butylbenzoic acids ester), 5,5- dimethyl -4,6- nonanediols two (4- p t butylbenzoic acids ester) and 5,5- dibutyl -4,6-Nonanediol two (4- p t butylbenzoic acids ester).

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