Synergistic insecticidal compositions

Synergistic insecticidal compositions

  • CN 1,343,093 A
  • Filed: 03/07/2000
  • Published: 04/03/2002
  • Est. Priority Date: 03/12/1999
  • Status: Abandoned Application
First Claim
Patent Images

1. , a kind of neuronal sodium channel antagonist of cooperative effective quantity and synergistic insecticidal composition of arylpyrrole insecticidal agent of comprising, wherein said neuronal sodium channel antagonist has following structure:

  • Wherein;

    A is CR 4R 5Or NR 6W is O or S;

    X, Y, Z, X '"'"', Y '"'"' and Z '"'"' are H independently of one another;

    Halogen atom;

    OH;

    CN;

    NO 2By one or more halogen atoms, C 1-C 3Alkoxyl, C 1-C 3Halogenated alkoxy, C 3-C 6Cycloalkyl, C 2-C 6The C of alkenyl oxy or the nonessential replacement of sulfonyloxy group 1-C 6Alkyl;

    By one or more halogen atoms, C 1-C 3Alkoxyl or C 3-C 6The C of the nonessential replacement of group of naphthene base 1-C 6Alkoxyl;

    C 1-C 6Alkoxy carbonyl;

    C 3-C 6Cycloalkyl carbonyl oxygen base;

    By one or more halogen atoms, C 1-C 4Alkyl or C 1-C 4The phenyl of the nonessential replacement of alkoxy base;

    By one or more C 1-C 3The amino carbonyl oxygen base of the nonessential replacement of alkyl group;

    C 1-C 6Alkoxyl carbonyl oxygen base;

    C 1-C 6Alkylsulfonyloxy;

    C 2-C 6Alkenyl;

    Or NR 12R 13M, p and q are 1,2,3,4 or 5 integer independently of one another;

    N is 0,1 or 2 integer;

    R is 1 or 2 integer;

    T is 1,2,3 or 4 integer;

    R, R 1, R 2, R 3, R 4And R 5Be H or C independently of one another 1-C 4Alkyl;

    R 6Be H, C 1-C 6Alkyl, C 1-C 6Haloalkyl, C 1-C 6Alkoxyalkyl, C 1-C 6Alkoxyl, C 1-C 6Halogenated alkoxy, C 2-C 6Alkenyl, C 2-C 6Alkynyl, C 1-C 6Alkyl-carbonyl, C 1-C 6Alkoxy carbonyl, C 1-C 6Alkylthio group or C 1-C 6Halogenated alkylthio;

    R 7And R 8Be H independently of one another;

    Halogen atom;

    C 1-C 6Alkyl;

    C 1-C 6Alkyl carbonyl oxy;

    Or by one or more halogen atoms, CN, NO 2, C 1-C 6Alkyl, C 2-C 6Haloalkyl, C 1-C 6Alkoxyl or C 1-C 6The phenyl of the nonessential replacement of halo alkoxy group;

    R 9And R 10Be H or C independently of one another 1-C 4Alkyl;

    R 11Be H, C 1-C 6Alkyl, C 1-C 6Haloalkyl, C 1-C 4Alkyl-carbonyl, C 1-C 6Alkoxy carbonyl or C 1-C 6Halo alkoxy carbonyl;

    R 12And R 13Be H or C independently of one another 1-C 6Alkyl;

    G is H;

    By one or more halogen atoms, C 1-C 4Alkoxyl, C 1-C 6Halogenated alkoxy, CN, NO 2S (O) uR 14, COR 15, CO 2R 16, phenyl or C 3-C 6The C of the nonessential replacement of group of naphthene base 1-C 6Alkyl;

    C 1-C 6Alkoxyl;

    C 1-C 6Halogenated alkoxy;

    CN;

    NO 2S (O) uR 17COR 18CO 2R 19By one or more halogen atoms, CN, C 1-C 3Haloalkyl or C 1-C 3The phenyl of the nonessential replacement of halo alkoxy group;

    C 3-C 6Cycloalkyl;

    Or thiophenyl;

    Q is by one or more halogen atoms, CN, SCN, NO 2, S (O) uR 20, C 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyalkyl, C 1-C 6Alkoxyl, C 1-C 6Halogenated alkoxy or NR 21R 22The phenyl of the nonessential replacement of group;

    U is 0,1 or 2 integer;

    R 14, R 15, R 16, R 18, R 19, R 21And R 22Be H or C independently of one another 1-C 6Alkyl;

    R 17And R 20Be C independently of one another 1-C 6Alkyl or C 1-C 6Haloalkyl;

    R 33Be CO 2R 34R 34Be H;

    C 1-C 6Alkyl;

    C 1-C 6Haloalkyl;

    Phenyl or halogenophenyl;

    X " and Y " be H independently of one another;

    Halogen atom;

    CN;

    SCN;

    By one or more halogen atoms, NO 2, CN, C 1-C 4Alkoxyl, C 1-C 4Alkylthio group, phenyl, halogenophenyl, C 1-C 4Alkyl sulphonyl, C 1-C 4Halogenated alkyl sulfonyl or C 1-C 4The C of the nonessential replacement of alkoxycarbonyl groups 1-C 6Alkyl;

    C 2-C 4Alkenyl;

    C 2-C 4Halogenated alkenyl;

    C 2-C 4Alkynyl;

    C 2-C 4The halo alkynyl;

    C 3-C 6Cycloalkyl;

    C 3-C 6Halogenated cycloalkyl;

    By one or more halogen atoms, CN, NO 2, C 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyl, C 1-C 4Halogenated alkoxy, C 1-C 4Alkylthio group, C 1-C 4Alkyl sulphonyl or C 1-C 4The phenyl of the nonessential replacement of halogenated alkyl sulfonyl group;

    C 1-C 4Alkyl-carbonyl;

    C 1-C 4Halogenated alkyl carbonyl;

    Or NR 28R 29G '"'"' is for being selected from X " the phenyl of the possible identical or different nonessential replacement of one or more groups;

    G '"'"' also can be one 5 yuan of hetero-aromatic rings or one 6 yuan of hetero-aromatic rings, wherein said 5 yuan of hetero-aromatic rings contain one or two hetero atom, this hetero atom is selected from 0 or 1 oxygen atom, 0 or 1 sulphur atom and 0,1 or 2 nitrogen-atoms, these 5 yuan of hetero-aromatic rings link to each other by carbon atom and by one or more may be identical or different be selected from X " the nonessential replacement of group;

    Described 6 yuan of hetero-aromatic rings contain one or two hetero atom, this hetero atom is selected from 0 or 1 oxygen atom, 0 or 1 sulphur atom and 0,1 or 2 nitrogen-atoms, these 6 yuan of hetero-aromatic rings link to each other by carbon atom and by one or more may be identical or different be selected from X " the nonessential replacement of group;

    Q '"'"' is H;

    By one or more halogen atoms, CN, C 1-C 3Alkoxyl, C 1-C 6The C of alkoxy carbonyl or the nonessential replacement of phenyl 1-C 6Alkyl, wherein phenyl is by one or more halogen atoms, CN, NO 2, C 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkyl sulphonyl or C 1-C 4The nonessential replacement of alkyl sulphinyl group;

    C 2-C 6Alkenyl;

    C 2-C 6Alkynyl;

    Or by the phenyl of 1 to 3 nonessential replacement of group, this 1 to 3 group can be identical or different, and it is selected from X ";

    R 23, R 24, R 25, R 26, R 27, R 28And R 29Be H or C independently of one another 1-C 4Alkyl;

    And dotted line configuration C-N represents two keys or a singly-bound;

    Or its stereoisomer;

    And arylpyrrole insecticidal agent wherein is the compound with structural formula VI, Wherein;

    Ar is Or Hal is Cl or Br;

    X is 1,2,3,4,5 or 6 integer;

    D is H;

    By one or more halogen atoms, CN, OH, C 1-C 4Alkoxyl, C 1-C 4Halogenated alkoxy, C 1-C 5Alkylthio group, C 1-C 4Alkyl carbonyl oxy, C 1-C 4Halogenated alkylthio, C 2-C 6Alkenyl carbonyl oxygen base, phenyl carbonyl oxygen base, halogenophenyl carbonyl oxygen base, phenoxy group, halogenated phenoxy, phenyl, halogenophenyl or C 1-C 3The C of the nonessential replacement of alkyl phenyl group 1-C 6Alkyl;

    C 2-C 6Alkenyl;

    C 2-C 6Halogenated alkenyl;

    CN;

    C 2-C 6Alkynyl;

    C 2-C 6The halo alkynyl;

    Two-(C 1-C 4Alkyl) amino carbonyl;

    Or C 3-C 6Polymethylene imino group carbonyl;

    L is H or halogen atom;

    M and M 1Be H independently of one another;

    Halogen atom;

    CN;

    NO 2C 1-C 4Alkyl;

    C 1-C 4Haloalkyl;

    C 1-C 4Alkoxyl;

    C 1-C 4Halogenated alkoxy;

    C 1-C 4Alkylthio group;

    C 1-C 4Halogenated alkylthio;

    C 1-C 4Alkyl sulphonyl;

    C 1-C 4Halogenated alkyl sulfonyl;

    C 1-C 4Alkyl-carbonyl;

    C 1-C 4Halogenated alkyl carbonyl;

    NR 35R 36Or as M and M 1When adjacent carbon atom was connected, they formed ring, wherein a MM with the carbon atom that links to each other 1Representative-OCH 2O-,-OCF 2O-or-CH=CH-CH=CH-;

    A '"'"' is O or S;

    R 30, R 31And R 32Be H independently of one another;

    Halogen atom;

    NO 2CHO;

    Or R 31And R 32Carbon atom that can be coupled forms ring, wherein a R together 31R 32Representative;

    L '"'"', L ", T and V be H, halogen atom, CN or NO independently of one another 2, but must L '"'"', L ", be no more than two among T or the V and be NO 2And R 35And R 36Be H or C independently of one another 1-C 4Alkyl.

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