Insecticidal anthranilamides

Insecticidal anthranilamides

  • CN 1,419,537 A
  • Filed: 03/20/2001
  • Published: 05/21/2003
  • Est. Priority Date: 03/22/2000
  • Status: Abandoned Application
First Claim
Patent Images

1. the anti-arthropodan method of platform comprises formula 1 compound with the Arthropodicidal effective dose, and their N-oxide compound or agricultural go up salt contact arthropods or their environment that is suitable for. WhereinA and B respectively do for oneself O or S;

  • Each J respectively does for oneself with 1-2 R 5Replace and 1-3 R 6Select the phenyl or naphthyl of replacement arbitrarily;

    Perhaps each J 8-of 5 or 6 yuan of hetero-aromatic rings or aromatics that respectively does for oneself, 9-or 10 yuan of assorted bicyclic ring system of condensed, wherein each ring or ring system can be with 1~

    4 R 7Select arbitrarily to replace;

    N is 1~

    4;

    R 1Be H;

    Or C 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 2-C 6Alkynyl or C 3-C 6Cycloalkyl, each available one or more following group is selected arbitrarily to replace;

    halogen, CN, NO 2, hydroxyl, C 1-C 4Alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 2-C 4Carbalkoxy C 1-C 4Alkylamino, C 2-C 8Dialkyl amido and C 3-C 6Naphthene amino;

    Or R 1Be C 2-C 6Alkyl-carbonyl, C 2-C 6Alkoxy carbonyl, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkylamino carbonyl or C (=A) J;

    R 2Be H;

    C 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 2-C 6Alkynyl, C 3-C 6Cycloalkyl, C 1-C 4Alkoxyl group, C 1-C 4Alkylamino, C 2-C 8Dialkylamino, C 3-C 6Cycloalkyl amino;

    C 2-C 6Alkoxy carbonyl or C 2-C 6Alkyl-carbonyl;

    R 3Be H;

    G;

    C 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 2-C 6Alkynyl, C 3-C 6Cycloalkyl, each available following group are selected arbitrarily to replace;

    halogen, G, CN, NO 2, hydroxyl, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 2-C 6Carbalkoxy, C 2-C 6Alkyl-carbonyl;

    C 3-C 6Trialkylsilkl, or phenyl, phenoxy group or 5 or 6 yuan of hetero-aromatic rings, each encircles available 1~

    3 and is selected from following group replacement;

    C respectively 1-C 4Alkyl, C 2-C 4Thiazolinyl, C 2-C 4Alkynyl, C 3-C 6Cycloalkyl, C 1-C 4Alkylhalide group, C 2-C 4Haloalkenyl, C 2-C 4Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, NO 2, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 1-C 4Alkylamino, C 2-C 8Dialkylamino, C 3-C 6Naphthene amino, C 3-C 6(alkyl) naphthene amino, C 2-C 4Alkyl-carbonyl, C 2-C 6Alkoxy carbonyl, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkylamino carbonyl or C 3-C 6Trialkylsilkl;

    C 1-C 4Alkoxyl group;

    C 1-C 4Alkylamino;

    C 2-C 8Dialkylamino;

    C 3-C 6Naphthene amino, C 2-C 6Carbalkoxy or C 2-C 6Alkyl-carbonyl;

    Or R 2And R 3Can form with the nitrogen that connects them and contain 2-6 carbon atom and optional another nitrogen, the ring of sulphur or Sauerstoffatom, said ring can be selected from C 1-C 2Alkyl, halogen, CN, NO 2And C 1-C 2The 1-4 of an alkoxyl group group is optional to be replaced;

    G is 5 or 6 yuan of non-aromatic carbocyclic or heterocycle, it comprise optional 1 or 2 be selected from C (=O), SO or S (O) 2Ring members, and the available C that is selected from 1-C 2Alkyl, halogen, CN, NO 2And C 1-C 2The 1-4 of an alkoxyl group substituting group is selected arbitrarily to replace;

    Each R 4Be respectively H, C 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 3-C 6Alkynyl, C 3-C 6Cycloalkyl, C 1-C 6Alkylhalide group, C 2-C 6Haloalkenyl, C 2-C 6Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, NO 2, hydroxyl, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 1-C 4The alkyl halide sulfenyl, C 1-C 4The alkylhalide group sulfinyl, C 1-C 4The alkylhalide group alkylsulfonyl, C 1-C 4Alkylamino, C 2-C 8Dialkylamino, C 3-C 6Naphthene amino, or C 3-C 6Trialkylsilkl;

    Or Each R 4The phenyl of respectively doing for oneself, benzyl or phenoxy group, each available following group are selected arbitrarily to replace;

    C 1-C 4Alkyl, C 2-C 4Thiazolinyl, C 2-C 4Alkynyl, C 3-C 6Cycloalkyl, C 1-C 4Alkylhalide group, C 2-C 4Haloalkenyl, C 2-C 4Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, NO 2, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 1-C 4Alkylamino, C 2-C 8Dialkyl amido, C 3-C 6Cycloalkyl amino, C 3-C 6(alkyl) cycloalkyl amino, C 2-C 4Alkyl-carbonyl, C 2-C 6Alkoxy carbonyl, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkyl amino carbonyl or C 3-C 6Trialkylsilkl;

    Each R 5C respectively does for oneself 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 2-C 6Alkynyl, C 3-C 6Cycloalkyl, C 1-C 6Alkylhalide group, C 2-C 6Haloalkenyl, C 2-C 6Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, CO 2H, CONH 2, NO 2, hydroxyl, C 1-C 6Alkoxyl group, C 1-C 6The halogen alkoxyl group, C 1-C 6Alkylthio, C 1-C 6Alkyl sulphinyl, C 1-C 6Alkyl sulphonyl, C 1-C 6The alkyl halide sulfenyl, C 1-C 6The alkylhalide group sulfinyl, C 1-C 6The alkylhalide group alkylsulfonyl, C 1-C 6Alkylamino, C 2-C 12Dialkylamino or C 3-C 6Cycloalkyl amino, C 2-C 6Alkyl-carbonyl, C 2-C 6Carbalkoxy, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkyl amino carbonyl, C 3-C 6Trialkylsilkl;

    Or As (R 5) 2When being connected in contiguous carbon atom, can be used as-OCF 2O-,-CF 2CF 2O-or-OCF 2CF 2O-connects together;

    Each R 6The H that respectively does for oneself, halogen, C 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 2-C 6Alkynyl, C 3-C 6Cycloalkyl, C 1-C 4Alkoxyl group or C 2-C 4Carbalkoxy, or Each R 6The phenyl of respectively doing for oneself, benzyl or phenoxy group, 8,9 or 10 yuan of condensed of 5 or 6 yuan of heterocycles or the aromatics bicyclic system of mixing, each encircles available 1~

    3 and is selected from following substituting group and selects arbitrarily to replace;

    C 1-C 4Alkyl, C 2-C 4Thiazolinyl, C 2-C 4Alkynyl, C 3-C 6Cycloalkyl, C 1-C 4Alkylhalide group, C 2-C 4Haloalkenyl, C 2-C 4Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, NO 2, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 1-C 4Alkylamino, C 2-C 8Dialkyl amido, C 3-C 6Cycloalkyl amino, C 3-C 6(alkyl) naphthene amino, C 2-C 4Alkyl-carbonyl, C 2-C 6Carbalkoxy, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkyl amino carbonyl or C 3-C 6Trialkylsilkl;

    Each R 7Be respectively H, C 1-C 6Alkyl, C 2-C 6Thiazolinyl, C 2-C 6Alkynyl, C 3-C 6Cycloalkyl, C 1-C 6Alkylhalide group, C 2-C 6Haloalkenyl, C 2-C 6Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, CO 2H, CONH 2, NO 2, hydroxyl, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Alkyl sulphonyl, C 1-C 4The alkyl halide sulfenyl, C 1-C 4The alkyl halide sulfinyl, C 1-C 4The alkylhalide group alkylsulfonyl, C 1-C 4Alkylamino, C 2-C 8Dialkyl amido, C 3-C 6Cycloalkyl amino, C 2-C 6Alkyl-carbonyl, C 2-C 6Carbalkoxy, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkyl amino carbonyl, C 3-C 6Trialkylsilkl;

    Or Each R 7The phenyl of respectively doing for oneself, benzyl, benzoyl, phenoxy group, the assorted bicyclic system of condensed of 5 or 6 yuan of hetero-aromatic ring bases or aromatics 8,9 or 10 yuan, each encircles available 1~

    3 and is selected from following group and selects arbitrarily to replace;

    C 1-C 4Alkyl, C 2-C 4Thiazolinyl, C 2-C 4Alkynyl, C 3-C 6Cycloalkyl, C 1-C 4Alkylhalide group, C 2-C 4Haloalkenyl, C 2-C 4Alkynyl halide;

    C 3-C 6The halogen cycloalkyl;

    Halogen, CN, NO 2, C 1-C 4Alkoxyl group, C 1-C 4The halogen alkoxyl group, C 1-C 4Alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4The alkane alkylsulfonyl, C 1-C 4Alkylamino, C 2-C 8Dialkylamino, C 3-C 6Naphthene amino, C 3-C 6(alkyl) cycloalkyl amino, C 2-C 4Alkyl-carbonyl, C 2-C 6Alkoxy carbonyl, C 2-C 6Alkyl amino-carbonyl, C 3-C 8Dialkyl amino carbonyl or C 3-C 6Trialkylsilkl;

    Condition is(1) when A and B both be O, R 2For HOr C 1-C 3Alkyl, R 3Be H or C 1-C 3Alkane and R 4Be H, halogen, C 1-C 6Alkyl, phenyl, hydroxyl or C 1-C 6During alkoxyl group, 1 R 5Not halogen, C 1-C 6Alkyl, hydroxyl or C 1-C 6Alkoxyl group;

    Or (2) J selects 1,2 of replacement, 3-thiadiazoles arbitrarily.

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