Method for synthesizing polymeric material, method for forming polymer thin film and method for forming interlayer insulating film
First Claim
1. A method for synthesizing a polymeric material comprising the steps of:
- forming a supramolecular structure by allowing a Lewis acid and a Lewis base in a solution state to self-organize through acid-base interaction; and
generating a polymer three-dimensional structure by polymerizing said Lewis acid and said Lewis base included in said supramolecular structure with said supramolecular structure used as a polymerization reaction field.
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Abstract
A Lewis acid-base reaction is caused, in a solution, between a first monomer corresponding to a Lewis acid and a second monomer corresponding to a Lewis base, so as to generate a monomer adduct in which the first monomer and the second monomer are bonded to each other through weak electric interaction. Next, the solution including the monomer adduct is applied on a substrate so as to form a supramolecular solid thin film made of the monomer adduct. Then, the supramolecular solid thin film is heated so as to cause a polymerization reaction between the first monomer and the second monomer within the supramolecular solid thin film, thereby forming a polymer thin film.
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Citations
19 Claims
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1. A method for synthesizing a polymeric material comprising the steps of:
forming a supramolecular structure by allowing a Lewis acid and a Lewis base in a solution state to self-organize through acid-base interaction; and
generating a polymer three-dimensional structure by polymerizing said Lewis acid and said Lewis base included in said supramolecular structure with said supramolecular structure used as a polymerization reaction field.- View Dependent Claims (2)
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3. A method for synthesizing a polymeric material comprising the steps of:
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generating a monomer adduct in which a first monomer corresponding to a Lewis acid and a second monomer corresponding to a Lewis base are bonded to each other through weak electric interaction by causing a Lewis acid-base reaction between said first monomer and said second monomer in a solution;
generating a supramolecular solid made of said monomer adduct by evaporating a solvent from said solution including said monomer adduct; and
generating a polymer solid by causing a polymerization reaction between said first monomer and said second monomer within said supramolecular solid. - View Dependent Claims (4, 5, 6, 7, 8, 9, 10)
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11. A method for forming a polymer thin film comprising the steps of:
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generating a monomer adduct in which a first monomer corresponding to a Lewis acid and a second monomer corresponding to a Lewis base are bonded to each other through weak electric interaction by causing a Lewis acid-base reaction between said first monomer and said second monomer in a solution;
forming a supramolecular solid thin film made of said monomer adduct by applying said solution including said monomer adduct on a substrate; and
forming a polymer thin film by causing a polymerization reaction between said first monomer and said second monomer within said supramolecular solid thin film by heating said supramolecular solid thin film. - View Dependent Claims (12, 13, 14, 15, 16, 17, 18)
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19-26. -26. (canceled)
Specification