SULFIDE SOLID ELECTROLYTE MATERIAL AND LITHIUM SOLID STATE BATTERY

• US 20130164631A1
• Filed: 07/11/2011
• Published: 06/27/2013
• Est. Priority Date: 08/26/2010
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Ohtomo, Takamasa, Kawamoto, Koji, Hama, Shigenori, Tsuchida, Yasushi, Kato, Yuki
• Granted Patent: US 9,356,315 B2
• Time in Patent Office: Days
• US Class Current: 429/319
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0562 Solid materials
• CPC Class Codes: H01M 2300/0065 Solid electrolytes
• CPC Class Codes: H01M 2300/0068 inorganic
• CPC Class Codes: H01M 2300/008 Halides
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The main object of the present invention is to provide a sulfide solid electrolyte material with high Li ion conductivity. The present invention solves the problem by providing a sulfide solid electrolyte material comprising an ion conductor with an ortho-composition, and LiI, characterized in that the sulfide solid electrolyte material is glass with a glass transition point.

Claims

1. A sulfide solid electrolyte material comprising an ion conductor an ion conductor having an anion structure of an ortho-composition as a main component to all anion structures, and LiI,

wherein the sulfide solid electrolyte material is glass with a glass transition point, and

the ion conductor contains Li, X (X is P, Si, Al or B), and S.

2. The sulfide solid electrolyte material according to claim 1, wherein a content of the LiI is within a range of 10 mol % to 30 mol %.

4. The sulfide solid electrolyte material according to claim 1, wherein the ion conductor contains Li, P, and S.

3. (canceled)

5. A sulfide solid electrolyte material comprising an ion conductor having an anion structure of an ortho-composition as a main component to all anion structures, and LiI, wherein the ion conductor contains oxygen.

6. The sulfide solid electrolyte material according to claim 5, wherein the oxygen of the ion conductor is derived from Li₂O.

7. The sulfide solid electrolyte material according to claim 5, wherein the ion conductor contains Li, X (X is P, Si, Ge, Al or B), S, and O.

8. The sulfide solid electrolyte material according to claim 5, wherein the ion conductor contains Li, P, S, and O.

12. A lithium solid state battery comprising a cathode active material layer containing a cathode active material, an anode active material layer containing an anode active material, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer,

wherein at least one of the cathode active material layer, the anode active material layer and the solid electrolyte layer contains the sulfide solid electrolyte material according to claim 5.

13. The lithium solid state battery according to claim 12, wherein the cathode active material layer contains the cathode active material with an electric potential of 2.8 V (vs Li) or more, and the sulfide solid electrolyte material.

9. A lithium solid state battery comprising a cathode active material layer containing a cathode active material, an anode active material layer containing an anode active material, and a solid electrolyte layer formed between the cathode active material layer and the anode active material layer,

wherein the cathode active material layer contains the cathode active material with an electric potential of 2.8 V (vs Li) or more, and a sulfide solid electrolyte material comprising an ion conductor having an anion structure of an ortho-composition as a main component to all anion structures and LiI.

10. The lithium solid state battery according to claim 9, wherein the ion conductor contains Li, X (X is P, Si, Ge, Al or B), and S.

11. The lithium solid state battery according to claim 9, wherein the ion conductor contains Li, P, and S.