Adhesion promoter

• US 7,662,482 B2
• Filed: 09/01/2005
• Issued: 02/16/2010
• Est. Priority Date: 09/01/2004
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Inventors: Walter, Barbara J., Wang, Yee Yang
• Primary Examiner(s): Seidleck; James
• Assistant Examiner(s): HAIDER, SAIRA BANO
• Application Number:
  US11/217,243
• Publication Number:
  US 20060051605A1
• Time in Patent Office: 1,629 Days
• Field of Search: 428/41.5, 428/522, 156/60, 156/327, 156/330, 525/242, 123/194.61, 568/763
• US Class Current: 428/522
• CPC Class Codes: B60R 13/0206 Arrangements of fasteners and clips specially adapted for attaching inner vehicle liners or mouldings devices for fastening or securing F16B
• CPC Class Codes: C09J 2477/006 in the substrate
• CPC Class Codes: C09J 5/02 involving pretreatment of the surfaces to be joined
• CPC Class Codes: F02M 35/10321 Plastics; Composites; Rubbers
• CPC Class Codes: F02M 35/10327 Metals; Alloys catalysts F02M27/02
• CPC Class Codes: F02M 35/1036 by welding, bonding or the like welding plastic materials together in general B29C65/02
• CPC Class Codes: Y10T 156/10 Methods of surface bonding and/or assembly therefor
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

The present invention provides an improved bonding system including an adhesion promoter that may be used to help adhesively bond two or more components together. The preferred use of the present adhesion promoter is in a transportation vehicle (e.g., automobile), and more particularly in an engine assembly for use in such vehicles. The present invention includes a bonded automobile engine assembly including at least one plastic component, an adhesive that bonds the plastic component to at least one separate component, and an adhesion promoter between the adhesive and the plastic component. Fasteners for attaching components are optionally employed. In one specific example, an intake manifold including a plastic component is bonded to an engine assembly.

Claims

1. A bonded automotive vehicle assembly, comprising:

at least one plastic component;

an adhesive for bonding the plastic component to at least one second component; and

an adhesion promoter between the adhesive and the plastic component, comprising at least;

a polyhydroxy compound;

a hydroxyalkyl methacrylate monomer; and

an anhydrous solvent.

2. The assembly of claim 1 wherein the hydroxyalkyl methacrylate monomer is present in the adhesion promoter from about 20 wt. % to about 30 wt. %.

3. The assembly of claim 2, wherein the polyhydroxy compound is a difuctional aromatic compound.

4. The assembly of claim 3, wherein the difunctional aromatic compound is resorcinol, wherein the resorcinol, and the resorcinol is present form about 40 to about 60% by weight of the adhesion promoter.

5. The assembly of claim 1, wherein the hydroxyalkyl methacrylate monomer comprises 2-hydroxyethyl methacrylate.

6. The assembly of claim 4, wherein the hydroxyalkyl methacrylate monomer is 2-hydroxyethyl methacrylate.

7. The assembly of claim 1, wherein

i) the polyhydroxy is present at a concentration from about 40 to about 60 wt %,

ii) the hydroxyalkyl methacrylate monomer is present at a concentration from about 20 to about 30 wt %, and

iii) the solvent is present at a concentration from about 20 to about 50 wt %.

8. The assembly of claims 1, wherein the solvent is selected from the group consisting of anhydrous methanol, anhydrous ethanol, anhydrous propanol, anhydrous isopropyl alcohol, anhydrous butanol, and any combination thereof, wherein the solvent is present at a concentration from about 20 wt. % to about 50 wt. % based on the total weight of the adhesion promoter.

9. The assembly of claims 1, wherein the solvent is present at a concentration from about 20 wt. % to about 50 wt. % based on the total weight of the adhesion promoter.

10. The assembly of claims 1, wherein the hydroxyalkyl methacrylate monomer is present from about 10 to about 40 wt. % based on the total weight of the adhesion promoter, and the ratio of polyhydroxy compound to hydroxyalkyl methacrylate monomer is between about 3:

1 and about 4;

3.

11. The assembly of claims 1, wherein the plastic component comprises reinforced nylon.

12. The assembly of claims 1, wherein the polyhydroxy compound includes resorcinol;

the hydroxyalkyl methacrylate monomer includes 2-hydroxyethyl methacrylate and the adhesion promoter includes

i) the resorcinol at a concentration from about 10 to about 70 wt %,

ii) the 2-hydroxyethyl methacrylate monomer at a concentration from about 10 to about 40 wt %, and

iii) from about 20 to about 50 wt % of an anhydrous ethanol.

13. The assembly of claims 1, wherein the adhesive comprises an acrylic resin.

14. The assembly of claims 12, wherein the adhesive comprises an epoxy adhesive.

15. A bonded automotive vehicle engine assembly, comprising:

at least one plastic intake manifold component;

an adhesive for bonding the intake manifold component to at least one different component; and

an adhesion promoter between the adhesive and the plastic intake manifold component, comprising at least;

resorcinol; and

hydroxyethyl (meth)acrylic monomer.