Methods and equipment for depositing hydrophilic coatings, and deposition technologies for thin films

• US 8,092,660 B2
• Filed: 05/16/2005
• Issued: 01/10/2012
• Est. Priority Date: 12/03/2004
• Status: Active Grant

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: Myli, Kari, Pfaff, Gary, Brownlee, James, German, John, Krisko, Annette, Hartig, Klaus
• Primary Examiner(s): Hendricks, Keith
• Assistant Examiner(s): BRAYTON, JOHN JOSEPH
• Application Number:
  US11/129,820
• Publication Number:
  US 20060118408A1
• Time in Patent Office: 2,430 Days
• Field of Search: 204/192.12, 204/192.15, 204/192.23, 204/192.26, 204/298.08
• US Class Current: 204/192.26
• CPC Class Codes: C03C 17/002 for flat glass, e.g. float glass
• CPC Class Codes: C03C 17/22 with other inorganic material C03C17/34, C03C17/44 take precedence
• CPC Class Codes: C03C 17/34 with at least two coatings having different compositions C03C17/44 takes precedence
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C03C 2218/154 by sputtering
• CPC Class Codes: C03C 2218/36 Underside coating of a glass sheet
• CPC Class Codes: C03C 2218/365 Coating different sides of a glass substrate
• CPC Class Codes: C23C 14/352 using more than one target C23C14/56 takes precedence
• CPC Class Codes: C23C 14/568 Transferring the substrates through a series of coating stations C23C14/562 takes precedence

Abstract

The invention provides certain embodiments that involve sputtering techniques for applying a mixed oxide film comprising silica and titania. In these embodiments, the techniques involve sputtering at least two targets in a common chamber (e.g., in a shared gaseous atmosphere). A first of these targets includes silicon, while a second of the targets includes titanium. Further, the invention provides embodiments involving a substrate bearing a hydrophilic coating, which can be deposited by sputtering or any other suitable thin film deposition technique. The invention also provides techniques and apparatuses useful for depositing a wide variety of coating types. For example, the invention provides thin film deposition technologies in which sputtering apparatuses or other thin film deposition apparatuses are employed.

Claims

1. A method for depositing coatings onto substrates, the method comprising:

a) providing a coater having a substrate transport system defining a path of substrate travel extending through the coater, wherein at least part of one or more lower sputtering target(s) are mounted below the path of substrate travel;

b) positioning a glass sheet on the transport system and conveying the glass sheet along the path of substrate travel, such that the glass sheet is conveyed over the one or more lower target(s); and

c) sputtering the one or more lower target(s) so as to deposit a coating upon a bottom major surface of the glass sheet, wherein the bottom major surface of the glass sheet once coated contacts at least one surface of the transport system, the coating comprising a desired film having a refractive index of between about 1.57 and about 1.8, wherein the desired film forms part or all of the coating on said bottom major surface, the coating having a total optical thickness of less than about 400 angstroms.

2. The method of claim 1, wherein the total optical thickness of the coating is less than about 300 angstroms.

3. The method of claim 1, wherein the total optical thickness of the coating is less than about 200 angstroms.

4. The method of claim 1, wherein each of the one or more lower target(s) is a rotary target having a central axis, each of the one or more lower target(s) being rotated about its central axis during said sputtering.

5. The method of claim 1, wherein the coating is deposited over an entirety of the bottom major surface of the glass sheet.

6. The method of claim 1, wherein the transport system comprises a transport roller, and the bottom major surface of the glass sheet once coated with the coating comes into direct contact with the transport roller as the glass sheet is being conveyed along the path of substrate travel.

7. A method for sputter depositing hydrophilic coatings, the method comprising:

a) providing a sputter deposition chamber in which there is mounted a first sputtering target having a first sputterable target material and a second sputtering target having a second sputterable target material, the deposition chamber containing a gaseous atmosphere, the deposition chamber including a substrate transport system comprising a plurality of transport rollers defining a path of substrate travel extending over the first and second targets, the first and second sputterable target materials being of different composition, the first sputterable target material comprising atoms of silicon, the second sputterable target material comprising atoms of titanium; and

b) providing a sheet-like substrate in the deposition chamber and positioning the substrate on the transport system and conveying the substrate along the path of substrate travel and sputtering the first and second targets upwardly such that a hydrophilic film having a refractive index of greater than 1.5 but less than 2.25 is deposited upon a bottom major surface of the substrate that contacts a plurality of the transport rollers while traveling along the path of substrate travel, the hydrophilic film comprising atoms of silicon, titanium, and oxygen, the hydrophilic film forming all or part of a coating sputtered upwardly onto the bottom major surface of the substrate, the coating having a total physical thickness of less than about 300 angstroms.

8. The method of claim 7, wherein the first and second targets are sputtered while maintaining the gaseous atmosphere at a pressure of between about 0.1 mtorr, and about 10 mtorr.

9. The method of claim 7, wherein the physical thickness is less than 200 angstroms.

10. The method of claim 9, wherein the physical thickness is less than about 160 angstroms.

11. The method of claim 7, wherein the first and second sputterable target materials are selected in conjunction with the gaseous atmosphere such that the hydrophilic film has between about 10 and about 50 atomic percent titanium, relative to the total number of metal atoms in the hydrophilic film.

12. The method of claim 7, wherein the first and second sputterable target materials are selected in conjunction with the gaseous atmosphere such that the hydrophilic film between about 90 and about 50 atomic percent silicon, relative to the total number of metal atoms in the hydrophilic film.

13. The method of claim 7, wherein the first and second targets are sputtered so as to emit generally converging fluxes of material.

14. The method of claim 13, wherein the first and second targets are provided with magnet assemblies that cause the fluxes to be generally converging.

15. The method of claim 7, wherein the first target is sputtered so as to emit a first flux of material, the first flux of material including silicon atoms, wherein the second target is sputtered so as to emit a second flux of material, the second flux of material including titanium atoms, and wherein the first and second fluxes of material flow into each other at least to a partial extent such that a mixed flow comprising silicon atoms and titanium atoms impinges at least one area of the substrate'"'"'s first major surface.

16. The method of claim 7, wherein the first target is sputtered so as to emit a first flux of material and the second target is sputtered so as to emit a second flux of material, the first target being provided with a first magnet assembly that causes the first flux to have a desired distribution oriented along a centerline that is offset from vertical by a first angle, the second target being provided with a second magnet assembly that causes the second flux to have a desired distribution oriented along a centerline that is offset from vertical by a second angle.

17. The method of claim 16, wherein the first and second angles are each at least about five degrees.

18. The method of claim 17, wherein the first and second angles are each between about five degrees and about 40 degrees.

19. The method of claim 7, wherein the first target is sputtered so as to emit a first flux of material, the first flux of material including silicon atoms, wherein the second target is sputtered so as to emit a second flux of material, the second flux of material including titanium atoms, wherein the first flux of material is emitted from the first target at a first rate of emission, wherein the second flux of material is emitted from the second target at a second rate of emission, and wherein the first and second rates of emission are different.

20. The method of claim 7, wherein a first power supply is operated to sputter the first target and a second power supply is operated to sputtering the second target.

21. The method of claim 20, wherein the first target is sputtered at a different power level than the second target.

22. The method of claim 20, wherein the first and second power supplies are DC power supplies operated so as to deliver direct current electricity to the first and second targets.

23. The method of claim 22, wherein the first and second DC power supplies are operated in a DC switching mode wherein direct current electricity is delivered only to the first target for a desired period, whereafter a switch is performed such that direct current electricity is delivered only to the second target for a desired period, whereafter another switch is performed such that direct current electricity is delivered only to the first target for a desired period, this switching being performed continuously for a desired period of time.

24. The method of claim 7, wherein the hydrophilic film is deposited over an entirety of the substrate'"'"'s first major surface.

25. The method of claim 7, wherein a single AC power supply is operated to deliver alternating current electricity to the first and second targets.

26. The method of claim 7, further comprising sputter depositing upon a second major surface of the substrate a low-emissivity coating that includes at least one infrared-reflective film comprising silver.

27. The method of claim 7, wherein the sputter deposition chamber is part of a large-area coater and the substrate has a major dimension of at least about 1 meter.

28. The method of claim 7, wherein the hydrophilic film comprises silica and titania.

29. A method for depositing coatings upwardly onto substrates, the method comprising:

a) providing a coater having a substrate transport system defining a path of substrate travel extending through the coater, the transport system including an intermediate transport roller, the intermediate transport roller being located between first and second coating deposition paths, the coater having first and second upward coating apparatuses mounted below the path of substrate travel, the first upward coating apparatus being adapted for emitting a different composition of coating material than the second upward coating apparatus, the intermediate transport roller serving as a divider member for separation of plumes from the first and second upward coating apparatuses;

b) positioning a glass sheet on the transport system and conveying the glass sheet along the path of substrate travel, such that the glass sheet is conveyed over the first and second upward coating apparatuses;

c) operating the first upward coating apparatus so as to emit a first flux of material upwardly along the first coating deposition path onto a bottom major surface of the glass sheet, thereby depositing a first partial coating on the bottom major surface of the glass sheet; and

d) operating the second upward coating apparatus so as to emit a second flux of material upwardly along the second coating deposition path onto the partially-coated bottom major surface of the glass sheet, thereby depositing a second partial coating, wherein the first flux of material has a different composition than the second flux of material, the first partial coating and/or the second partial coating comprising film having a refractive index of greater than 1.55, wherein all the upward coating deposition apparatuses in the coater are upward sputter deposition apparatuses and the method is performed such that no more than a total physical thickness of about 300 angstroms is sputter deposited on the bottom major surface of the glass sheet, and wherein said bottom major surface once coated comes into direct contact with at least one surface of the transport system.

30. The method of claim 29, wherein the coater includes a deposition chamber defining an interior cavity, the path of substrate travel extends through the deposition chamber, and the first and second upward coating apparatuses are disposed at least in part within the deposition chamber.

31. The method of claim 29, wherein the first upward coating apparatus is a first sputter deposition apparatus comprising a first sputtering target, and the second upward coating apparatus is a second sputter deposition apparatus comprising a second sputtering target, wherein the first sputtering target has a length, the first coating deposition path extends through a first gap that has a length, the first sputtering target is positioned directly beneath the first gap so that the length of the first sputtering target is generally parallel to the length of the first gap, and wherein the second sputtering target has a length, the second coating deposition path extends through a second gap that has a length, the second sputtering target is positioned directly beneath the second gap so that the length of the second sputtering target is generally parallel to the length of the second gap.

32. The method of claim 29, wherein the first partial coating is deposited over an entirety of the bottom major surface of the glass sheet.

33. The method of claim 29, wherein the coater is a large-area coater and the glass sheet conveyed through the coater has a major dimension of at least about 1 meter.

34. The method of claim 29, wherein the coater includes a series of downward coating apparatuses positioned on a common side of the path of substrate travel such that the downward coating apparatuses of said series are above the path of substrate travel, the downward coating apparatuses of said series being operated so as to deposit a low-emissivity coating on a top major surface of the glass sheet.