Dyeing composition comprising a fatty substance, a non-ionic guar gum, an amphoteric surfactant and a non-ionic or anionic surfactant, and an oxidizing agent, dyeing process and suitable device

• US 10,226,411 B2
• Filed: 08/02/2013
• Issued: 03/12/2019
• Est. Priority Date: 08/02/2012
• Status: Active Grant

• Current Assignee: L'Oreal SA
• Original Assignee: L'Oreal SA
• Inventors: Charrier, Delphine, Fack, Geraldine
• Primary Examiner(s): Elhilo, Eisa B
• Application Number:
  US14/418,736
• Publication Number:
  US 20150257993A1
• Time in Patent Office: 2,048 Days
• Field of Search: 8405
• CPC Class Codes: A61K 2800/4324 in preparations for permanently dyeing the hair
• CPC Class Codes: A61K 2800/5422 nonionic
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 2800/594 Mixtures of polymers
• CPC Class Codes: A61K 2800/596 Mixtures of surface active compounds
• CPC Class Codes: A61K 2800/882 Mixing prior to application
• CPC Class Codes: A61K 8/31 Hydrocarbons
• CPC Class Codes: A61K 8/342 Alcohols having more than seven atoms in an unbroken chain
• CPC Class Codes: A61K 8/39 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61K 8/41 Amines
• CPC Class Codes: A61K 8/411 Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
• CPC Class Codes: A61K 8/415 Aminophenols
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/60 Sugars; Derivatives thereof
• CPC Class Codes: A61K 8/737 Galactomannans, e.g. guar; Derivatives thereof
• CPC Class Codes: A61K 8/92 Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
• CPC Class Codes: A61K 8/922 of vegetable origin
• CPC Class Codes: A61Q 5/10 Preparations for permanently dyeing the hair

Abstract

The subject of the present invention is a composition for dyeing human keratin fibers such as the hair, comprising: (a) at least one oxidation dye precursor; (b) at least one first amphoteric or zwitterionic surfactant; (c) at least one second non-ionic or anionic surfactant; (d) one or more fatty substances; (e) at least one cationic polymer; (f) at least one non-ionic guar gum; (g) at least one oxidizing agent other than atmospheric oxygen. The present invention also relates to a process for dying human keratin fibers, in which this composition is applied to said fibers, and also to a suitable multicompartment device.

Claims

1. A composition for dyeing keratin fibers, comprising:

at least one oxidation dye precursor;

at least one amphoteric or zwitterionic surfactant;

at least one non-ionic or anionic surfactant;

at least one fatty substance chosen from liquid petroleum jelly, C₆-C₁₆ alkanes, polydecenes, liquid fatty acid or fatty alcohol esters, or mixtures thereof;

at least one cationic polymer;

at least one non-ionic guar gum, wherein the at least one non-ionic guar gum is unmodified, or is modified with C₁-C₆ hydroxyalkyl groups, optionally comprising groups comprising at least one C₆-C₃₀ fatty chain; and

at least one oxidizing agent other than atmospheric oxygen,

wherein the weight ratio of the amount of amphoteric and/or zwitterionic surfactant to the amount of non-ionic and/or anionic surfactant ranges from 0.1 to 10 (0.1;

10).

2. The composition according to claim 1, wherein the at least one oxidation dye precursor is chosen from oxidation bases or salts thereof.

3. The composition according to claim 1, wherein the at least one oxidation dye precursor is chosen from couplers or the addition salts of these couplers with an acid.

4. The composition according to claim 1, wherein the at least one amphoteric or zwitterionic surfactant is chosen from derivatives of optionally quaternized aliphatic secondary or tertiary amines, wherein the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group.

5. The composition according to claim 4, wherein the at least one amphoteric or zwitterionic surfactant is chosen from:

(C₈-C₂₀)alkylbetaines,

(C₈-C₂₀)alkylsulfobetaines,

(C₈-C₂₀)alkylam ido(C₃-C₈)alkylbetaines,

(C₈-C₂₀)alkylam ido(C₆-C₈)alkylsulfobetaines,

the compounds of formula (B1);

R_a—

C(O)—

NH—

CH₂—

CH₂—

N⁺(R_b)(R_c)—

CH₂C(O)O⁻

, M⁺, X⁻

 

 

(B1)

wherein;

R_a is chosen from a C₁₀-C₃₀ alkyl or alkenyl group derived from an acid R_a—

COOH, heptyl, nonyl or undecyl group;

R_b is a β

-hydroxyethyl group; and

R_c is a carboxymethyl group;

M⁺ is chosen from a cationic counterion derived from an alkali metal or alkaline-earth metal or an ammonium ion or an ion derived from an organic amine, and

X⁻

is chosen from an organic or inorganic anionic counterion chosen from halides, acetates, phosphates, nitrates, (C₁-C₄)alkyl sulfates, (C₁-C₄)alkyl- or (C₁-C₄)alkylarylsulfonates;

or alternatively M⁺ and X<sup>−

are absent,</sup>

the compounds of formula (B2);

R_a′

—

C(O)—

NH—

CH₂—

CH₂—

N(B)(B′

) 

 

(B2)

wherein;

B is the group —

CH₂—

CH₂—

O—

X′

;

B′

is the group —

(CH₂)_zY′

, with z equal to the integer 1 or 2;

X′

is chosen from the groups —

CH₂—

C(O)OH, —

CH₂—

C(O)OZ′

, —

CH₂—

CH₂—

C(O)OH, —

CH₂—

CH₂—

C(O)OZ′

, or a hydrogen atom;

Y′

is chosen from the groups —

C(O)OH, —

C(O)OZ′

, —

CH₂—

CH(OH)—

SO₃H— and

CH₂—

CH(OH)—

SO₃—

Z′

;

Z′

is chosen from a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine; and

R_a′

represents a C₁₀-C₃₀ alkyl or alkenyl group of an acid R_a′

—

C(O)OH, an alkyl group, or an unsaturated C₁₇ group, and

the compounds of formula (B′

2);

R_a″

—

NH—

CH(Y″

)—

(CH₂)n—

C(O)—

NH—

(CH₂)n′

—

N(R_d)(R_e) 

 

(B′

2)

wherein;

Y″

is chosen from the groups —

C(O)OH, —

C(O)OZ″

, —

CH₂—

CH(OH)—

SO₃H, —

CH₂—

CH(OH)—

SO₃—

Z″

;

R_d and R_e, independently of each other, are chosen from C₁-C₄ alkyl or hydroxyalkyl radical;

Z″

is chosen from a cationic counterion derived from an alkali metal or alkaline-earth metal, an ammonium ion or an ion derived from an organic amine;

R_a″

is chosen from a C₁₀-C₃₀ alkyl or alkenyl group of an acid R_a″

—

C(O)OH; and

n and n′

, independently of each other, are integers ranging from 1 to 3.

6. The composition according to claim 1, wherein the at least one non-ionic or anionic surfactant is non-ionic and chosen from the following, alone or as mixtures:

oxyalkylenated (C₈-C₂₄)alkylphenols;

saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C₈-C₃₀ alcohols;

saturated or unsaturated, linear or branched, oxyalkylenated C₈-C₃₀ amides;

esters of saturated or unsaturated, linear or branched, C₈-C₃₀ acids and of polyethylene glycols;

esters of saturated or unsaturated, linear or branched, C₈-C₃₀ acids and of sorbitol;

fatty acid esters of sucrose;

(C₈-C₃₀)alkylpolyglycosides, (C₈-C₃₀)alkenylpolyglycosides, optionally oxyalkylenated (0 to 10 oxyalkylene units) and comprising 1 to 15 glucose units, (C₈-C₃₀)alkylglucoside esters;

oxyethylenated and saturated or unsaturated vegetable oils;

condensates of ethylene oxide and/or of propylene oxide, inter alia, alone or as mixtures;

N—

(C₈-C₃₀)alkylglucamine derivatives and N—

(C₈-C₃₀)acyl-methylglucamine derivatives;

aldobionamides;

amine oxides;

or

oxyethylenated and/or oxypropylenated silicones.

7. The composition according to claims 1, comprising anionic surfactants chosen from alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkyl sulfonates, alkylamide sulfonates, alkylaryl sulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acyl sarcosinates, acyl glutamates, alkyl sulfosuccinamates, acyl isethionates and N-acyl taurates;

salts of alkyl monoesters of polyglycoside-polycarboxylic acids, acyl lactylates, salts of D-galactoside uronic acids, salts of alkyl ether carboxylic acids, salts of alkylaryl ether carboxylic acids, salts of alkylamido ether carboxylic acids, and the corresponding non-salified forms of these compounds, the alkyl and acyl groups of all these compounds comprising from 6 to 40 carbon atoms, and the aryl group denoting a phenyl group.

8. The composition according to claim 1, comprising at least one non-ionic surfactant and at least one anionic surfactant.

9. The composition according to claim 1, wherein the at least one fatty substance is present in an amount ranging from about 10% to about 70% by weight, relative to the total weight of the composition.

10. The composition according to claim 1, wherein the at least one cationic polymer has a charge density of at least 1 meq/g.

11. The composition according to claim 1, wherein the at least one cationic polymer is chosen from the following polymers, alone or as mixtures:

(1) Homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of formula (I), (II), (III) or (IV) below;

12. The composition according to claim 11, wherein the at least one cationic polymer is chosen from the polymers (1), (7), (8) and (9), alone or as mixtures.

13. The composition according to claim 1, wherein the at least one cationic polymer is present in an amount ranging from about 0.01% to about 10% by weight, relative to the weight of the composition.

14. The composition according to claim 1, wherein the at least one non-ionic guar gum is present in an amount ranging from about 0.001% to about 10% by weight, relative to the total weight of the composition.

15. The composition according to claim 1, wherein the at least one oxidizing agent other than atmospheric oxygen is hydrogen peroxide.

16. A process for dyeing keratin fibers, comprising:

(a) preparing the dye composition by mixing;

a first composition free of an oxidizing agent other than atmospheric oxygen, comprising at least one oxidation dye precursor; and

a second composition comprising at least one oxidizing agent other than atmospheric oxygen,

wherein at least one of the first or second compositions comprises at least one fatty substance, at least one cationic polymer, at least one first amphoteric or zwitterionic surfactant, at least one non-ionic or anionic surfactant and at least one non-ionic guar gum,

wherein the at least one non-ionic guar gum is unmodified, or is modified with C₁-C₆ hydroxyalkyl groups, optionally comprising groups comprising at least one C₆-C₃₀ fatty chain,

further wherein the weight ratio of the amount of amphoteric and/or zwitterionic surfactant to the amount of non-ionic and/or anionic surfactant ranges from 0.1 to 10 (0.1;

10); and

(b) applying said dye composition to said keratin fibers.

17. The process according to claim 16, wherein the second composition comprising at least one oxidizing agent comprises at least one cationic polymer.

18. The process according to claim 16, wherein the fatty substance is present in at least 10% the mixture of the first composition and of the second composition, relative to the weight of the mixture.

19. A device for mixing and using a composition for dyeing keratin fibers, comprising:

a first compartment containing a composition free of oxidizing agent other than atmospheric oxygen, comprising at least one oxidation dye precursor; and

a second compartment containing an oxidizing composition;

wherein at least one of the compositions comprises at least one fatty substance, at least one cationic polymer, at least one amphoteric or zwitterionic surfactant, at least one non-ionic or anionic surfactant and at least one non-ionic guar gum, wherein the at least one non-ionic guar gum is unmodified, or is modified with C₁-C₆ hydroxyalkyl groups, optionally comprising groups comprising at least one C₆-C₃₀ fatty chain; and

wherein the composition in the first compartment and the composition in the second compartment are mixed before use.