Methods and apparatus for forming a graded fade zone on a substrate and articles produced thereby

• US 20020127343A1
• Filed: 11/13/2001
• Published: 09/12/2002
• Est. Priority Date: 12/18/1997
• Status: Abandoned Application

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Kutilek, Luke A., Scriven, Roger L.
• Application Number:
  US10/007,979
• Publication Number:
  US 20020127343A1
• Time in Patent Office: Days
• US Class Current: 427/420
• CPC Class Codes: B05B 12/18 using fluids, e.g. gas streams
• CPC Class Codes: C03C 17/002 for flat glass, e.g. float glass
• CPC Class Codes: C03C 17/23 Oxides C03C17/02 takes precedence
• CPC Class Codes: C03C 17/25 by deposition from the liquid phase
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3694 one layer having a composition gradient through its thickness
• CPC Class Codes: C03C 2217/23 Mixtures

Abstract

An apparatus for forming a graduated coating on a substrate includes a coating station positioned along a conveyor. The coating station includes a first coating dispenser pivotally mounted on a first support and at least one exhaust hood. The first coating dispenser is positioned such that an axis through the delivery end of the first coating dispenser subtends the substrate at a predetermined angle. A method for forming a graduated fade zone on a substrate surface includes positioning a coating dispenser adjacent one side of the substrate, angling the coating dispenser toward the other side of the substrate and supplying a coating material to the coating dispenser such that the coating material is deposited onto the substrate to form a graded fade zone on the substrate.

Claims

1. A method for forming a graded coating on a surface of a substrate having a first end and a second end, comprising the steps of:

positioning at least one first coating dispenser relative the first end of the substrate;

directing said first coating dispenser toward the substrate such that an axis extending through a delivery end of said first coating dispenser subtends a predetermined angle with the substrate; and

supplying a first coating material to said first coating dispenser such that the coating material is deposited onto the substrate to form a graduated coating on the substrate.

2. The method as claimed in claim 1, including heating the substrate such that the first coating material pyrolyzes on the substrate.

3. The method as claimed in claim 1, including positioning a first exhaust hood on one side of said first coating dispenser and positioning a second exhaust hood on the other side of said first coating dispenser.

4. The method as claimed in claim 1, including positioning at least one second coating dispenser spaced from said first coating dispenser and supplying a second coating material to said second coating dispenser.

5. The method as claimed in claim 4, including directing said second coating dispenser toward the substrate such that an axis extending through a delivery end of said second coating dispenser subtends a second predetermined angle with the substrate.

6. The method as claimed in claim 4, wherein the second coating material is different from the first coating material.

7. The method as claimed in claim 5, wherein the second predetermined angle is different from the first predetermined angle.

8. The method as claimed in claim 1 further including the step of displacing the first coating dispenser and substrate relative to one another.

9. An article of manufacture formed by the method of claim 1.

10. A method of forming a graded coating on a surface of a substrate, comprising the steps of:

providing a plurality of spaced coating dispensers, each coating dispenser configured to provide a spray pattern having a center on the substrate;

directing coating material through the coating dispensers; and

positioning the coating dispensers to form a plurality of overlapping coated areas on the substrate as the substrate moves relative to the coating dispensers to form a graded coating on the substrate.

11. The method as claimed in claim 10, including positioning the coating dispensers such that a coated area formed by one coating dispenser on the substrate does not extend beyond the center of the spray pattern of an adjacent coating dispenser.

12. The method as claimed in claim 10, wherein the spray patterns are elongated spray patterns having a major axis and the method includes positioning the coating dispensers such that the major axes of the coating dispensers are substantially parallel.

13. The method as claimed in claim 10, including positioning said coating dispensers such that the coating has a tapered region on each side of the coating.

14. The method as claimed in claim 13, including dividing the coated substrate into a plurality of pieces, each piece having a tapered region.

15. An article of manufacture formed by the method of claim 10.

17. The apparatus as claimed in claim 16, further including a heated chamber, wherein said conveyor is configured to transport the substrate to be coated from said heated chamber to said first coating dispenser.

18. The apparatus as claimed in claim 16, including a second coating dispenser spaced from said first coating dispenser, with said second coating dispenser positioned to subtend a second predetermined angle with the supporting surface.

19. The apparatus as claimed in claim 16, wherein said predetermined angle is between about 20-40 .

20. The apparatus as claimed in claim 16, including a first exhaust hood and a second exhaust hood, with said first coating dispenser located between said first and second exhaust hoods.

21. The apparatus as claimed in claim 16, including means for causing relative movement between the substrate and said first coating dispenser.

22. The apparatus as claimed in claim 20, including a third exhaust hood and at least one second coating dispenser, wherein said second coating dispenser is located between said second and third exhaust hoods.

24. The apparatus as claimed in claim 23, wherein said at least one exhaust slot is tapered.

26. The apparatus as claimed in claim 25, wherein each coating dispenser is configured to provide an elongated spray pattern having a major axis and wherein the major axes of said coating dispensers are substantially parallel.

28. The article of manufacture as claimed in claim 27, wherein the coating has a tapered region on each side of the coating.

29. The article of manufacture as claimed in claim 27, wherein the glass substrate is an architectural window or an automotive transparency.

16. An apparatus for forming a graded coating on a surface of a substrate, comprising:

a supporting surface;

at least one first coating dispenser having a delivery end;

a source of coating material in flow communication with said first coating dispenser;

at least one exhaust hood mounted in a spaced, predetermined relation to said first coating dispenser; and

means for mounting said first coating dispenser relative to said supporting surface, wherein no shield is located between said first coating dispenser and said support surface, and

wherein an axis extending through said delivery end subtends a predetermined angle with said supporting surface such that coating material is directed from said discharge end onto said substrate surface to form a graded coating on the substrate surface.

23. An apparatus for forming a graded coating on a surface of a substrate, comprising:

a tapered coating delivery slot having a first end and a second end, with a width of said delivery slot decreasing from said first end to said second end; and

at least one exhaust slot spaced from said tapered delivery slot.

25. An apparatus for forming a graded coating on a surface of a substrate, comprising:

a plurality of spaced coating dispensers, each configured to provide a spray pattern having a center to form a plurality of overlapping coated areas on the substrate as the substrate moves relative to said coating dispensers,

wherein said coating dispensers are positioned such that a coated area formed by one coating dispenser on the substrate does not extend beyond the center of the spray pattern of an adjacent coating dispenser.

27. An article of manufacture, comprising:

a substrate having a surface; and

a graded coating pyrolytically deposited on the surface of the substrate, the coating having varying thicknesses along a predetermined length of the coating.

30. A vehicle having a window with a coating pyrolytically deposited on a surface of the window to form a graded coating on the surface of the window.

31. The vehicle as claimed in claim 30, wherein the surface is an outer window surface.