Method for the production of conductive composite material

• US 20030160352A1
• Filed: 04/04/2003
• Published: 08/28/2003
• Est. Priority Date: 02/17/2000
• Status: Abandoned Application

• Current Assignee: Nedstack Holding B.V.
• Original Assignee: Nedstack Holding B.V.
• Inventors: Middelman, Erik
• Application Number:
  US10/204,132
• Publication Number:
  US 20030160352A1
• Time in Patent Office: Days
• US Class Current: 264/104
• CPC Class Codes: B29C 43/22 of articles of indefinite length
• CPC Class Codes: B29C 43/34 Feeding the material to the mould or the compression means B29C43/085 takes precedence
• CPC Class Codes: B29C 70/882 partly or totally electrically conductive, e.g. for EMI shielding conductive floors or floor coverings H05F3/025; EMI shielding in general H05K9/00
• CPC Class Codes: B29K 2995/0005 Conductive
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/043 involving compressing or compaction
• CPC Class Codes: H01M 4/0433 Molding
• CPC Class Codes: H01M 4/0483 by methods including the handling of a melt H01M4/0438, take precedence
• CPC Class Codes: H01M 4/64 Carriers or collectors
• CPC Class Codes: H01M 4/8875 Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The invention is related to a method for the production of sheet like material that can be used in applications where polymer based material has to conduct electric current at low impedance, especially for application in electrodes, like the electrodes of polymer electrolyte membrane (PEM) fuel cells, the sheet material being electrically conductive composite material comprising a non conductive polymer binder and electrically conductive compounds. The method according to this invention has as its objective to provide a method for large-scale production of electrical conductive sheet like material in which the disadvantages of the prior art are avoided.

Claims

1. A method for the production of an electrical conductive intermediate product comprising electrical conductive solids, and a non conductive polymer binder wherein the intermediate material is produced by means of a continuous pressing machine

2. A method according to claim 1 wherein the raw materials are mixed and homogenized as powders to form a powder mixture.

3. A method according to claim 1 or 2 wherein the continuous pressing machine is an isobaric double belt press.

4. A method according to claim 1 or 2 wherein the continuous pressing machine is an isochoric double belt press.

5. A method according to any of the preceding claims wherein the non conductive polymer is a fluorine containing polymer like PTFE, PVDF, PVF, PFA, FEP or THV.

6. A method according to claim 5 wherein the preferred fluorinated polymer is PVDF.

7. A method according to any of the preceding claims wherein the non conductive polymer is a poly olefin like LD-PE, HD-PE, UHMWPE, PP,

8. a method according to claim 5 wherein the preferred olefin polymer is HD-PE.

9. A method according to any of the preceding claims wherein the sheet like intermediate product has porosity between 0 and 90%.

10. A method according to any of the preceding claims wherein the intermediate product is reinforced with fibers like glass fibers, metal fibers, carbon fibers, graphite fibers or aramid fibers

11. A method according to any of the preceding claims wherein the intermediate product is used for the production of shaped parts like electrodes or fuel cell plates or the conductive part of fuel cell plates

12. A method according to any of the preceding claims wherein shaped parts of conductive composite material are pulverized and this powder is used for the production of the conductive intermediate product.

13. A method according to any of the preceding claims wherein the production process contains;

mixing of powder like raw materials with or without an low viscous liquid, distribution of the powder mixture or paste on an foil like carrier, a endless process belt or a drum, optionally drying, heating to a temperature above the melting point, or if there is no melting point above the Tg of de non conductive polymer, forming to a sheet like material by rolling or pressing, and cooling to a temperature below the melting point or the Tg of the non conducting polymer.

14. A method of forming shaped parts wherein the process comprises the following steps;

Cutting the intermediate product to the right size, weight or volume to prepare a pre-form

Heating of the preform to a temperature above Tm if semi crystalline polymer is used or above Tg if amorphous polymer is used.

Placing the heated perform in a suitable mold in a suitable pressing machine like a hydraulic press, the mold having a temperature below Tg or Tm of the polymer and preferably avoiding direct contact between the mold surface and the heated preform prior to closing of the mold.

Closing of the mold at high pressure to form the perform to a negative of the mold halves

Release from the mold.