Optical oxygen concentration measurement method and optical oxygen concentration measuring sensor

• US 20030235513A1
• Filed: 06/12/2003
• Published: 12/25/2003
• Est. Priority Date: 06/21/2002
• Status: Abandoned Application

• Current Assignee: Japan Aerospace Exploration Agency
• Original Assignee: National Aerospace Laboratory Of Japan
• Inventors: Okura, Ichiro, Nishide, Hiroyuki, Asai, Keisuke
• Application Number:
  US10/459,468
• Publication Number:
  US 20030235513A1
• Time in Patent Office: Days
• US Class Current: 422/400
• CPC Class Codes: G01N 2021/6432 Quenching
• CPC Class Codes: G01N 2021/7786 Fluorescence
• CPC Class Codes: G01N 21/6428 Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" in vivo A61B5/00; immunoassay G01N33/53
• CPC Class Codes: G01N 21/783 for analysing gases
• CPC Class Codes: G01N 2201/06193 Secundary in-situ sources, e.g. fluorescent particles

Abstract

The present invention provides an optical oxygen concentration measurement method and optical oxygen concentration measuring sensor wherein a light-absorbing dye-molecule layer whose absorption spectrum varies depending on the bonding with oxygen molecules is combined with a light-emitting layer, and the oxygen concentration of the ambient fluid can be measured. The light-absorbing layer 4 laminated to an oxygen-quenching light-emitting layer 3 is a film comprising a cobalt-porphyrin complex (CoP) or other light-absorbing dye molecule 7 whose absorption spectrum varies depending on the bonding with oxygen molecules. When the degree of overlap with the light emission spectrum or excitation (absorption) spectrum of the light-emitting layer 3 varies as a result of a variation in the absorption spectrum possessed by the light-absorbing layer 4, the light intensity of output light varies in accordance with the degree of overlap, and the oxygen concentration of the ambient fluid can be measured. These measurement method and measuring sensor can be applied not only to optical fiber sensors, but also to wind tunnel experiments and the like as pressure-sensitive paints.

Claims

1. An optical oxygen concentration measurement method, comprising:

using a combination of a light-emitting layer for receiving excitation light and emitting light, and a light-absorbing layer whose light absorption spectrum varies depending on the degree of bonding with oxygen molecules, which varies in accordance with the oxygen concentration; and

measuring the oxygen concentration by detecting the light intensity of output light that varies based on the partial absorption of light emitted by the light-emitting layer or incident light for initiating light emission in the light-emitting layer during passage through the light-absorbing layer.

2. The optical oxygen concentration measurement method according to claim 1, wherein the light partially absorbed by the light-absorbing layer is the incident light for initiating light emission in the light-emitting layer;

the output light is light that is emitted by the light-emitting layer; and

the overlap of the excitation spectrum of the light-emitting layer and the light absorption spectrum varies in accordance with variations in the light absorption spectrum.

3. The optical oxygen concentration measurement method according to claim 1, wherein the light partially absorbed by the light-absorbing layer is the light that is emitted by the light-emitting layer;

the output light is light emitted by the light-emitting layer that is transmitted through the light-absorbing layer; and

the overlap of the light emission spectrum of the light-emitting layer and the light absorption spectrum varies in accordance with variations in the light absorption spectrum.

4. The optical oxygen concentration measurement method according to claim 1, wherein the light-emitting layer is a light-emitting dye-molecule layer in which the light intensity of the emitted light is caused to vary by a reaction with oxygen molecules, which varies in accordance with the oxygen concentration.

5. The optical oxygen concentration measurement method according to claim 1, wherein the light-absorbing layer is a layer that comprises a cobalt-porphyrin complex as the light-absorbing dye molecule.

6. The optical oxygen concentration measurement method according to claim 1, which is applied to measure the oxygen concentration of a gas or liquid that comprises the oxygen molecules, or the pressure of a gas that comprises the oxygen molecules.

7. An optical oxygen concentration measuring sensor, comprising:

a light-emitting layer for receiving excitation light and emitting light; and

a light-absorbing layer whose light absorption spectrum varies depending on the degree of bonding with oxygen molecules, which itself varies in accordance with the oxygen concentration,

wherein variations are created in the light intensity of output light on the basis of partial absorption when light emitted by the light-emitting layer, or incident light for initiating light emission in the light-emitting layer, passes through the light-absorbing layer.

8. The optical oxygen concentration measuring sensor according to claim 7, wherein the light partially absorbed by the light-absorbing layer is the incident light for initiating light emission in the light-emitting layer;

the output light is light that is emitted by the light-emitting layer; and

the overlap of the excitation spectrum of the light-emitting layer and the light absorption spectrum varies in accordance with variations in the light absorption spectrum.

9. The optical oxygen concentration measuring sensor according to claim 7, wherein the light partially absorbed by the light-absorbing layer is the light that is emitted by the light-emitting layer;

the output light is light emitted by the light-emitting layer that is transmitted through the light-absorbing layer; and

the overlap of the light emission spectrum of the light-emitting layer and the light absorption spectrum varies in accordance with variations in the light absorption spectrum.

10. The optical oxygen concentration measuring sensor according to claim 7, wherein the light-emitting layer is a light-emitting dye-molecule layer in which the light intensity of the emitted light is caused to vary by a reaction with oxygen molecules, which varies in accordance with the oxygen concentration.

11. The optical oxygen concentration measuring sensor according to claim 7, wherein the light-absorbing layer is a layer that comprises a cobalt-porphyrin complex as the light-absorbing dye molecule.

12. The optical oxygen concentration measuring sensor according to claim 7, which is applied to measure the oxygen concentration of a gas or liquid that comprises the oxygen molecules, or the pressure of a gas that comprises the oxygen molecules.