Elastomer gum polymer systems
First Claim
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1. A composition comprising:
- (a) a continuous phase of polymer; and
(b) a dispersed phase, said dispersed phase comprising a plurality of gum portions dispersed in said continuous phase, wherein each said gum portion is dispersed from elastomer precursor gum having a glass transition temperature, a decomposition temperature, and, at a temperature having a value that is not less than said glass transition temperature and not greater than said decomposition temperature, a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said derived elastomer.
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Abstract
Elastomer precursor gum (for any of fluoroelastomer, acrylic acid ester rubber/polyacrylate rubber, ethylene acrylic rubber, silicone, nitrile butyl rubber, hydrogenated nitrile rubber, natural rubber, polyurethane, and styrene butadiene rubber) and non-gum polymer are admixed with optional electrically conductive particulate and/or optional filler to provide either a continuous phase of polymer with dispersed gum portions, a continuous phase of elastomer precursor gum with dispersed polymer portions, or an interpenetrated structure of elastomer precursor gum and polymer. Curing is optionally enabled with techniques such as electron beam radiation.
129 Citations
78 Claims
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1. A composition comprising:
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(a) a continuous phase of polymer; and
(b) a dispersed phase, said dispersed phase comprising a plurality of gum portions dispersed in said continuous phase, wherein each said gum portion is dispersed from elastomer precursor gum having a glass transition temperature, a decomposition temperature, and, at a temperature having a value that is not less than said glass transition temperature and not greater than said decomposition temperature, a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said derived elastomer. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9)
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10. A composition comprising:
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(a) a continuous phase of elastomer precursor gum having a glass transition temperature, a decomposition temperature, and, at a temperature having a value that is not less than said glass transition temperature and not greater than said decomposition temperature, a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said derived elastomer; and
(b) a dispersed phase of polymer, said dispersed phase comprising a plurality of polymer portions dispersed in said continuous phase. - View Dependent Claims (11, 12, 13, 14, 15, 16, 17, 18, 53)
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19. A composition, comprising:
an interpenetrated structure of molecules of elastomer precursor gum molecules and molecules of a polymer, wherein said elastomer precursor gum molecules are intermixed into said interpenetrated structure from elastomer precursor gum having a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for an elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said elastomer. - View Dependent Claims (20, 21, 22, 23, 24, 25, 26)
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27. A composition comprising:
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(a) a continuous phase of polymer; and
(b) a dispersed phase of vulcanized elastomer, said dispersed phase comprising a plurality of vulcanized elastomer portions dispersed in said continuous phase, wherein each said vulcanized elastomer portion is cured from elastomer precursor gum having a glass transition temperature, a decomposition temperature, and, at a temperature having a value that is not less than said glass transition temperature and not greater than said decomposition temperature, a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said derived elastomer. - View Dependent Claims (28, 29, 30, 31, 32, 33, 34, 35)
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36. A composition comprising:
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(a) a continuous phase of vulcanized elastomer cured from elastomer precursor gum having a glass transition temperature, a decomposition temperature, and, at a temperature having a value that is not less than said glass transition temperature and not greater than said decomposition temperature, a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said derived elastomer; and
(b) a dispersed phase of polymer, said dispersed phase comprising a plurality of polymer portions dispersed in said continuous phase. - View Dependent Claims (37, 38, 39, 40, 41, 42, 43, 44)
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45. A composition, comprising:
an interpenetrated structure of molecules of vulcanized elastomer and molecules of a polymer, wherein said vulcanized elastomer is cured from elastomer precursor gum having a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for an elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said elastomer. - View Dependent Claims (46, 47, 48, 49, 50, 51, 52)
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54. A method for making an admixture composition, comprising:
(a) admixing (i) a polymer; and
(ii) elastomer precursor gum having a glass transition temperature, a decomposition temperature, and, at a temperature having a value that is not less than said glass transition temperature and not greater than said decomposition temperature, a compressive set value from about 0 to about 5 percent of a mathematical difference between a non-vulcanized compressive set value for elastomer derived from said elastomer precursor gum and a fully-vulcanized compressive set value for said derived elastomer. - View Dependent Claims (55, 56, 57, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78)
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58. The method of any of claims and 55 and 56 wherein said fluororelastomer is selected from the group consisting of
(i) vinylidene fluoride/hexafluoropropylene copolymer fluoroelastomer having from about 66 weight percent to about 69 weight percent fluorine and a Mooney viscosity of from about 0 to about 130 ML1+10 at 121 degrees Celsius, (ii) vinylidene fluoride/perfluorovinyl ether/tetrafluoroethylene terpolymer fluoroelastomer having at least one cure site monomer and from about 64 weight percent to about 67 weight percent fluorine and a Mooney viscosity of from about 50 to about 100 ML1+10 at 121 degrees Celsius, (iii) tetrafluoroethylene/propylene/vinylidene fluoride terpolymer fluoroelastomer having from about 59 weight percent to about 63 weight percent fluorine and a Mooney viscosity of from about 25 to about 45 ML1+10 at 121 degrees Celsius, (iv) tetrafluoroethylene/ethylene/perfluorovinyl ether terpolymer fluoroelastomer having at least one cure site monomer and from about 60 weight percent to about 65 weight percent fluorine and a Mooney viscosity of from about 40 to about 80 ML1+10 at 121 degrees Celsius, (v) vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene terpolymer fluoroelastomer having at least one cure site monomer and from about 66 weight percent to about 72.5 weight percent fluorine and a Mooney viscosity of from about 15 to about 90 ML1+10 at 121 degrees Celsius, (vi) tetrafluoroethylene/propylene copolymer fluoroelastomer having about 57 weight percent fluorine and a Mooney viscosity of from about 25 to about 115 ML1+10 at 121 degrees Celsius, (vii) tetrafluoroethylene/ethylene/perfluorovinyl ether/vinylidene fluoride tetrapolymer fluoroelastomer having at least one cure site monomer and from about 59 weight percent to about 64 weight percent fluorine and a Mooney viscosity of from about 30 to about 70 ML1+10 at 121 degrees Celsius, (viii) tetrafluoroethylene/perfluorovinyl ether copolymer fluoroelastomer having at least one cure site monomer and from about 69 weight percent to about 71 weight percent fluorine and a Mooney viscosity of from about 60 to about 120 ML1+10 at 121 degrees Celsius, fluoroelastomer corresponding to the formula
[-TFEq-HFPr-VdFs-]dand (ix) combinations thereof, wherein TFE is essentially a tetrafluoroethyl block, HFP is essentially a hexfluoropropyl block, and VdF is essentially a vinylidyl fluoride block, and products qd and rd and sd collectively provide proportions of TFE, HFP, and VdF whose values are within element 101 of FIG. 1 .
Specification