Corrosion Resistant Object Having an Outer Layer of a Precious Metal

• US 20080274372A1
• Filed: 06/14/2006
• Published: 11/06/2008
• Est. Priority Date: 06/15/2005
• Status: Abandoned Application

• Current Assignee: Danfoss A/S
• Original Assignee: Danfoss A/S
• Inventors: Gillesberg, Bo, Pedersen, Hans Joergen, Christensen, Erik
• Application Number:
  US11/917,206
• Publication Number:
  US 20080274372A1
• Time in Patent Office: Days
• US Class Current: 428/662
• CPC Class Codes: C23F 13/12 Electrodes characterised by the material C23F13/16 takes precedence
• CPC Class Codes: C25B 11/051 Electrodes formed of electrocatalysts on a substrate or carrier
• CPC Class Codes: C25C 7/02 Electrodes consumable anodes for the refining the metals C25C1/00 - C25C5/00; Connections thereof
• CPC Class Codes: Y10T 428/12819 Group VB metal-base component

Abstract

An object comprising a conductive body part, a layer comprising a refractory metal (e.g. tantalum), and a layer comprising a precious metal (e.g. platinum or gold). A metallurgical bond has been formed between the layers. Thereby oxidation of the refractory metal layer, and thereby passivation of the object, can be avoided even with small amounts of precious metal. This lowers the material costs while ensuring desired corrosion resistant properties. The object is suitable for an electrode to be used in a corrosive environment, in particular when a large conductivity is needed. Also a method of manufacturing the object. The metallurgical bond is provided by heating the object.

Claims

1. An object comprising:

an electrically conductive body part,

a first layer comprising a refractory metal or an alloy of a refractory metal, said first layer at least substantially covering an outer surface of the body part, and

a second layer comprising a precious metal, said second layer at least substantially covering the first layer,

wherein a metallurgical bond has been formed between the first and the second layer.

2. The object according to claim 1, wherein the first layer has a thickness within the interval 2 μ

m to 200 μ

m.

3. The object according to claim 1, wherein the second layer has a thickness within the interval 0.01 μ

m to 5 μ

m.

4. The object according to claim 1, wherein the first layer comprises tantalum or an alloy of tantalum.

5. The object according to claim 1, wherein the body part comprises a metal or an alloy, and wherein the first layer comprises an alloy of a refractory metal and a metal present in the body part.

6. The object according to claim 1, wherein the body part has a conductivity within the interval 0.01×

10⁶ Ω

<sup>−

1</sup>cm<sup>−

1</sup> to 0.65×

10⁶ Ω

<sup>−

1</sup>cm<sup>−

1</sup>.

7. The object according to claim 1, wherein the object is or forms part of an electrode.

8. A method of forming an object, the method comprising the steps of:

providing an electrically conductive body part,

applying a first layer to a surface part of the body part, said first layer comprising a refractory metal or an alloy of a refractory metal,

applying a second layer on top of the first layer, said second layer comprising a precious metal, and

heating at least the second layer during or after applying the second layer, thereby forming a metallurgical bond between the first and second layer.

9. The method according to claim 8, wherein the heating step is performed by heating at least the second layer to a temperature within the interval 400°

C. to 1500°

C.

10. The method according to claim 8, wherein the step of applying the second layer is performed using evaporation techniques.

11. The method according to claim 8, wherein the step of applying the second layer is performed by means of galvanic electrolysis.

12. The method according to claim 8, wherein the body part comprises a metal or an alloy, and wherein the step of applying the first layer is performed in such a way that the resulting first layer comprises an alloy of a refractory metal and a metal present in the body part.

13. A method of preventing formation of an oxide layer on an electrode, the method comprising the steps of:

providing an electrode having an electrically conducting body part,

applying a first layer to a surface part of the electrode, said first layer comprising a refractory metal or an alloy of a refractory metal,

applying a second layer on top of the first layer, said second layer comprising a precious metal, and

heating at least the second layer during or after applying the second layer, thereby forming a metallurgical bond between the first and second layer, thereby preventing formation of an oxide layer on the first layer.