Exhaust After-treatment System Having Low Temperature SCR Catalyst

• US 20160032803A1
• Filed: 07/29/2014
• Published: 02/04/2016
• Est. Priority Date: 07/29/2014
• Status: Abandoned Application

• Current Assignee: Tenneco Automotive Operating Company Incorporated (Apollo Global Management, Inc.)
• Original Assignee: Tenneco Automotive Operating Company Incorporated (Apollo Global Management, Inc.)
• Inventors: Ettireddy, Padmanabha Reddy, Kotrba, Adam J., Spinks, Thomas, Thirupathi, Boningari, Smirniotis, Panagiotis
• Application Number:
  US14/445,686
• Publication Number:
  US 20160032803A1
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B01J 2229/186 not in framework positions
• CPC Class Codes: B01J 29/7057 Zeolite Beta
• CPC Class Codes: B01J 29/7615 Zeolite Beta
• CPC Class Codes: B01J 29/7815 Zeolite Beta
• CPC Class Codes: B01J 35/19 Catalysts containing parts with different compositions
• CPC Class Codes: B01J 37/0201 Impregnation
• CPC Class Codes: B01J 37/035 Precipitation on carriers
• CPC Class Codes: F01N 13/009 having two or more separate purifying devices arranged in series
• CPC Class Codes: F01N 2240/25 an ammonia generator
• CPC Class Codes: F01N 2370/04 Zeolitic material
• CPC Class Codes: F01N 2610/02 the substance being ammonia or urea
• CPC Class Codes: F01N 2610/1453 Sprayers or atomisers; Arrangement thereof in the exhaust apparatus
• CPC Class Codes: F01N 2610/146 Control thereof, e.g. control of injectors or injection valves
• CPC Class Codes: F01N 3/021 by means of filters
• CPC Class Codes: F01N 3/035 with catalytic reactors , e.g. catalysed diesel particulate filters
• CPC Class Codes: F01N 3/106 Auxiliary oxidation catalysts
• CPC Class Codes: F01N 3/2053 By-passing catalytic reactors, e.g. to prevent overheating
• CPC Class Codes: F01N 3/2073 with means for generating a reducing substance from the exhaust gases
• CPC Class Codes: F01N 3/208 Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

An aftertreatment system for treating exhaust gas discharged from a combustion engine, the aftertreatment system comprising a low temperature selective-catalytic-reduction catalyst, wherein the low-temperature selective-catalytic-reduction catalyst is a mixture of catalytic metals provided on a beta-zeolite support material, the mixture of catalytic metals being at least one mixture selected from Cu and Ce, Mn and Ce, Mn and Fe, Cu and W, Mn and W, and Ce and W.

Claims

1. An aftertreatment system for treating exhaust gas discharged from a combustion engine, the aftertreatment system comprising a low temperature selective-catalytic-reduction catalyst, wherein the low-temperature selective-catalytic-reduction catalyst is a mixture of catalytic metals provided on a beta-zeolite support material, the mixture of catalytic metals being at least one mixture selected from Cu and Ce, Mn and Ce, Mn and Fe, Cu and W, Mn and W, and Ce and W.

2. The aftertreatment system according to claim 1, wherein a loading of each metal in each mixture is in the range of 0.5 to 20 wt %, with the balance comprising the beta-zeolite support material.

3. The aftertreatment system according to claim 1, wherein a mass ratio of an amount of a first catalytic metal relative to an amount of a second catalytic metal in each mixture is in the range of 1.5 to 40.

4. The aftertreatment system according to claim 1, wherein a mass ratio of an amount of a first catalytic metal relative to an amount of a second catalytic metal in each mixture is in the range of 3 to 25.

5. The aftertreatment system according to claim 1, wherein a mass ratio of an amount of a first catalytic metal relative to an amount of a second catalytic metal in each mixture is in the range of 5 to 20.

6. The aftertreatment system according to claim 1, wherein the mixtures of catalytic metal are formed by at least one method selected from the group consisting of cation exchange, deposition precipitation, incipient wetness, and wet impregnation.

7. The aftertreatment system according to claim 1, wherein the mixture of catalytic metals in the low-temperature selective-catalytic-reduction catalyst further includes a third metal selected from Cu, Ce, Mn, Fe, and W.

8. The aftertreatment system according to claim 1, wherein the mixture of catalytic metals in the low-temperature selective-catalytic-reduction catalyst further includes an alkali metal.

9. The aftertreatment system according to claim 1, wherein the mixture of catalytic metals in the low-temperature selective-catalytic-reduction catalyst further includes a third metal selected from the lanthanide group metals.

10. An aftertreatment system for treating exhaust gas discharged from a combustion engine, the aftertreatment system comprising:

at least one of an oxidation catalyst and a particulate filter configured to receive exhaust gas;

a first selective-catalytic-reduction catalyst;

the low temperature selective-catalytic reduction catalyst of claim 1;

a valve disposed upstream of the first selective-catalytic-reduction catalyst and the at least one of the oxidation catalyst and particulate filter, the valve connected to first and second exhaust flow paths and movable between a first position allowing exhaust gas to flow through the first exhaust flow path and bypass the second exhaust flow path and a second position allowing exhaust gas to flow through the second exhaust flow path and bypass the first exhaust flow path, the low temperature selective-catalytic-reduction catalyst being disposed in the second exhaust flow path; and

a control module in communication with the valve and configured to cause the valve to move between the first and second positions based on at least one of a temperature of the exhaust gas and a temperature of the combustion engine.

12. The aftertreatment system of claim 10, wherein the first and second exhaust flow paths are disposed upstream of the first selective-catalytic-reduction catalyst.

13. The aftertreatment system of claim 10, wherein the second exhaust flow path includes a fluid injection port disposed upstream of the low temperature selective-catalytic-reduction catalyst.

15. The aftertreatment system of claim 10, wherein the at least one of the oxidation catalyst and particulate filter is disposed in the first exhaust flow path.

16. The aftertreatment system of claim 15, wherein the first selective-catalytic-reduction catalyst is disposed in the first exhaust flow path.

42. The aftertreatment system according to claim 1, further comprising a particulate filter that includes the low-temperature selective catalytic reduction catalyst.

44. The aftertreatment system according to claim 1, wherein the low-temperature selective catalytic reduction catalyst is stable at temperatures up to 500 C.

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24. An aftertreatment system for treating exhaust gas discharged from a combustion engine, the aftertreatment system comprising a low temperature selective-catalytic-reduction catalyst, wherein the low-temperature selective-catalytic-reduction catalyst includes a first catalytic metal and a second catalytic metal dispersed on a beta-zeolite support material, wherein the first and second catalytic metals are each selected from the group consisting of Cu, Ce, Mn, Fe, and W.

25. The aftertreatment system according to claim 24, wherein the low-temperature selective-catalytic-reduction catalyst further includes a third catalytic metal selected from the group of Cu, Ce, Mn, Fe, and W.

26. The aftertreatment system according to claim 24, wherein a loading of each of the first and second catalytic metals is in the range of 0.5 to 20 wt %, with the balance comprising the beta-zeolite support material.

27. The aftertreatment system according to claim 24, wherein a mass ratio of an amount of the first catalytic metal relative to an amount of the second catalytic metal is in the range of 1.5 to 40.

28. The aftertreatment system according to claim 24, wherein a mass ratio of an amount of the first catalytic metal relative to an amount of the second catalytic metal is in the range of 3 to 25.

29. The aftertreatment system according to claim 24, wherein a mass ratio of an amount of the first catalytic metal relative to an amount of the second catalytic metal is in the range of 5 to 20.

30. The aftertreatment system according to claim 24, wherein the first and second catalytic metals are dispersed on the beta-zeolite support material by at least one method selected from the group consisting of cation exchange, deposition precipitation, incipient wetness, and wet impregnation.

37. An aftertreatment system for treating exhaust gas discharged from a combustion engine, the aftertreatment system comprising:

a first exhaust gas flow path receiving a first portion of the exhaust gas from the combustion engine, the first exhaust gas flow path including an ammonia generator and an injection port through which the ammonia is injected into the exhaust gas;

a second exhaust gas flow path receiving a second portion of the exhaust gas from the combustion engine and including at least one of a oxidation catalyst and a particulate filter;

a first selective-catalytic-reduction catalyst receiving exhaust gas from the first and second exhaust gas flow paths; and

a second selective-catalytic-reduction catalyst receiving exhaust gas from the first and second exhaust gas flow paths, the second selective-catalytic-reduction catalyst being the low-temperature selective-catalytic-reduction catalyst according to claim 24.

38. The aftertreatment system of claim 37, wherein the second selective-catalytic-reduction catalyst is disposed downstream of the first selective-catalytic-reduction catalyst.

39. The aftertreatment system of claim 37, wherein the first exhaust gas flow path includes an inlet disposed downstream of a turbocharger.

40. The aftertreatment system of claim 37, wherein the first exhaust gas flow path includes an inlet disposed upstream of a turbocharger.

43. The aftertreatment system according to claim 24, further comprising a particulate filter that includes the low-temperature selective catalytic reduction catalyst.

45. The aftertreatment system according to claim 24, wherein the low-temperature selective catalytic reduction catalyst is stable at temperatures up to 500 C.

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41. The aftertreatment system of claim 36, wherein the injection port is disposed downstream of the ammonia generator.