Method for capturing carbon dioxide from biomass pyrolysis process

• US 8,404,909 B2
• Filed: 12/09/2009
• Issued: 03/26/2013
• Est. Priority Date: 12/09/2009
• Status: Expired due to Fees

• Current Assignee: Chevron USA Incorporated (Chevron Corp.)
• Original Assignee: Chevron USA Incorporated (Chevron Corp.)
• Inventors: Jadhav, Raja A
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US12/634,401
• Publication Number:
  US 20110132737A1
• Time in Patent Office: 1,203 Days
• Field of Search: 201/2.5, 201/3, 201/16, 201/17, 201/21, 201/29, 201/30, 585/240, 585/242, 423/230
• US Class Current: 585/240
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: C01B 32/50 Carbon dioxide
• CPC Class Codes: C10B 49/20 in dispersed form
• CPC Class Codes: C10B 53/02 of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A method of biomass pyrolysis is described which includes chemical looping of combustion char so that carbon dioxide can be captured from the combustion of the char as well as producing useable compounds from pyrolyzing biomass in a pyrolysis reactor including a metal oxide carrier particles which is in operative cooperation with a char combustor and oxidation reactor and separator for separating carbon dioxide from the flue gas produced by the char combustor.

Claims

1. A method for capturing carbon dioxide from the combustion of char produced in biomass pyrolysis, the method comprising the steps of:

(a) pyrolyzing biomass in a pyrolysis reactor in the presence of heat energy carrier particles including metal oxide sorbents to produce char, pyrolysis oil vapors and metal oxide sorbents;

(b) separating the pyrolysis oil vapors from the char and heat energy carrier particles and transferring the char and heat energy carrier particles to a char combustor;

(c) combusting the char in the char combustor in the presence of oxidized metal oxide sorbents and producing a flue gas stream of carbon dioxide and water vapor and a stream of heat energy carrier particles including reduced metal oxide sorbents;

(d) separating the flue gas stream from the stream of heat energy carrier particles including the reduced metal oxide sorbents;

(e) separating the flue gas stream into carbon dioxide and water vapor and capturing a stream of carbon dioxide;

(f) oxidizing a first portion of the stream of heat energy carrier particles including reduced metal oxide sorbents received from the char combustor in an oxidation reactor in the presence of air to produce a regenerated stream of heat energy carrier particles including oxidized metal oxide sorbents to be used in step (c); and

(g) recycling to the pyrolysis reactor of step (a) a second portion of the stream of heat energy carrier particles including reduced metal oxide sorbents.

2. The method of claim 1 wherein:

the metal oxide sorbent includes a metal oxide supported on a substrate, the metal oxide being selected from one or more of the group consisting of NiO, CuO, CO₃O₄, Fe₂O₃, Mn₂O₃ and CaSO₄.

3. The method of claim 2 wherein:

the substrate is selected from the group of consisting of one or more of alumina, silica, aluminosilica, titania and zirconia.

4. The method of claim 1 wherein:

the metal oxide sorbents further have metals incorporated therein selected from one or more of the group consisting of Ni, Mo, Co, Cr, W, Rh, Ir, Re, and Ru.

5. The method of claim 1 wherein:

the heat energy carrier particles further include pyrolysis oil upgrading catalyst particles.

6. The method of claim 5 wherein:

the pyrolysis oil upgrading catalyst particles are selected from one or more of the group consisting of zeolites, alumina, transition metal catalysts and mesoporous materials.

7. The method of claim 6 wherein:

the zeolite is selected from one or more of the group consisting of H-ZSM-5, H-Y, H-mordenite, silicalite, and silica-alumina.

8. The method of claim 6 wherein:

the alumina is selected from one or more of the group consisting of α

-alumina and γ

-alumina.

9. The method of claim 6 wherein:

the transition metal catalyst is selected from one or more of the group consisting of Fe/Cr, FeCr₂O₄, and Fe₂O₃.

10. The method of claim 6 wherein:

the mesoporous material is selected from one or more of the group consisting of Al-MCM-41 and Cu/Al-MCM-41.

11. The method of claim 1 wherein:

the pyrolysis oil vapor is condensed into a liquid pyrolysis oil and non-condensable off-gases produced in the pyrolysis of the biomass are used as a fuel in the char combustor and as a fluidization medium in the pyrolysis reactor.